Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

Fatma Sevin; Ikay Sökmen; Bülent Düz; Philip B. Shevlin

doi:10.1016/S0040-4039(03)00579-3

Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

Fatma Sevin
, Ikay Sökmen
, Bülent Düz
, Philip B. Shevlin

Hacettepe University
Auburn University

Araştırma çıktısı: Dergiye katkı › Makale › Hakemli

7 Alıntılar (Scopus)

Özet

Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	3405-3407
Sayfa sayısı	3
Dergi	Tetrahedron Letters
Hacim	44
Basın numarası	16
DOI'lar	https://doi.org/10.1016/S0040-4039(03)00579-3
Yayın durumu	Yayınlandı - 14 Nis 2003

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10.1016/S0040-4039(03)00579-3

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title = "Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol",

abstract = "Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.",

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AU - Sevin, Fatma

AU - Sökmen, Ikay

AU - Düz, Bülent

AU - Shevlin, Philip B.

PY - 2003/4/14

Y1 - 2003/4/14

N2 - Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.

AB - Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.

UR - https://www.scopus.com/pages/publications/0037436931

UR - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=performanshacettepe&SrcAuth=WosAPI&KeyUT=WOS:000182150500040&DestLinkType=FullRecord&DestApp=WOS_CPL

U2 - 10.1016/S0040-4039(03)00579-3

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JF - Tetrahedron Letters

IS - 16

ER -

Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

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