The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

E. Kendi; D. Ülkü

doi:10.1524/zkri.1976.144.1-6.91

The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

E. Kendi
, D. Ülkü

Hacettepe Üniversitesi

Hacettepe University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

23 Alıntılar (Scopus)

Özet

The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	91-96
Sayfa sayısı	6
Dergi	Zeitschrift fur Kristallographie - New Crystal Structures
Hacim	144
Basın numarası	1-6
DOI'lar	https://doi.org/10.1524/zkri.1976.144.1-6.91
Yayın durumu	Yayınlandı - 1976

Belgeye Erişim

10.1524/zkri.1976.144.1-6.91

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title = "The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2",

abstract = "The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) {\AA}, c = 8.082(6) {\AA}; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.",

author = "E. Kendi and D. {\"U}lk{\"u}",

year = "1976",

doi = "10.1524/zkri.1976.144.1-6.91",

language = "English",

volume = "144",

pages = "91--96",

journal = "Zeitschrift fur Kristallographie - New Crystal Structures",

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T1 - The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

AU - Kendi, E.

AU - Ülkü, D.

PY - 1976

Y1 - 1976

N2 - The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

AB - The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

UR - https://www.scopus.com/pages/publications/84942960467

U2 - 10.1524/zkri.1976.144.1-6.91

DO - 10.1524/zkri.1976.144.1-6.91

M3 - Article

AN - SCOPUS:84942960467

SN - 1433-7266

VL - 144

SP - 91

EP - 96

JO - Zeitschrift fur Kristallographie - New Crystal Structures

JF - Zeitschrift fur Kristallographie - New Crystal Structures

IS - 1-6

ER -

The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

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