Magnetically-recoverable Pd-immobilized layered double hydroxide-iron oxide nanocomposite catalyst for carbon-carbon cross-coupling reactions

Ahmet N. Ay; Natalya V. Abramova; Deniz Konuk; Olga L. Lependina; Viacheslav I. Sokolov; Birgül Zümreoglu-Karan

doi:10.1016/j.inoche.2012.10.020

Magnetically-recoverable Pd-immobilized layered double hydroxide-iron oxide nanocomposite catalyst for carbon-carbon cross-coupling reactions

Ahmet N. Ay
, Natalya V. Abramova
, Deniz Konuk
, Olga L. Lependina
, Viacheslav I. Sokolov
, Birgül Zümreoglu-Karan

Anorganik Kimya Anabilim Dalı

Russian Academy of Sciences
Hacettepe University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

27 Alıntılar (Scopus)

Özet

A novel magnetic composite catalyst has been prepared by immobilizing a palladium(0) complex, Pd₂(dba)₃, onto Mg-Al-layered double hydroxide shell supported on magnetite core. This new catalyst was characterized by XRD, TEM, EDX, FTIR, XPS, thermogravimetry and microanalytical techniques and magnetometric measurements. The performance of the catalyst was tested in the Heck and Suzuki reactions and confirmed to be efficient in the cross-coupling of aryl iodides under mild conditions.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	64-68
Sayfa sayısı	5
Dergi	Inorganic Chemistry Communications
Hacim	27
DOI'lar	https://doi.org/10.1016/j.inoche.2012.10.020
Yayın durumu	Yayınlandı - Oca 2013

Belgeye Erişim

10.1016/j.inoche.2012.10.020

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title = "Magnetically-recoverable Pd-immobilized layered double hydroxide-iron oxide nanocomposite catalyst for carbon-carbon cross-coupling reactions",

abstract = "A novel magnetic composite catalyst has been prepared by immobilizing a palladium(0) complex, Pd2(dba)3, onto Mg-Al-layered double hydroxide shell supported on magnetite core. This new catalyst was characterized by XRD, TEM, EDX, FTIR, XPS, thermogravimetry and microanalytical techniques and magnetometric measurements. The performance of the catalyst was tested in the Heck and Suzuki reactions and confirmed to be efficient in the cross-coupling of aryl iodides under mild conditions.",

keywords = "Core-shell, Heck and Suzuki reactions, Heterogeneous catalyst, Layered double hydroxide, Magnetic catalyst, Palladium",

author = "Ay, \{Ahmet N.\} and Abramova, \{Natalya V.\} and Deniz Konuk and Lependina, \{Olga L.\} and Sokolov, \{Viacheslav I.\} and Birg{\"u}l Z{\"u}mreoglu-Karan",

year = "2013",

month = jan,

doi = "10.1016/j.inoche.2012.10.020",

language = "English",

volume = "27",

pages = "64--68",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Magnetically-recoverable Pd-immobilized layered double hydroxide-iron oxide nanocomposite catalyst for carbon-carbon cross-coupling reactions

AU - Ay, Ahmet N.

AU - Abramova, Natalya V.

AU - Konuk, Deniz

AU - Lependina, Olga L.

AU - Sokolov, Viacheslav I.

AU - Zümreoglu-Karan, Birgül

PY - 2013/1

Y1 - 2013/1

N2 - A novel magnetic composite catalyst has been prepared by immobilizing a palladium(0) complex, Pd2(dba)3, onto Mg-Al-layered double hydroxide shell supported on magnetite core. This new catalyst was characterized by XRD, TEM, EDX, FTIR, XPS, thermogravimetry and microanalytical techniques and magnetometric measurements. The performance of the catalyst was tested in the Heck and Suzuki reactions and confirmed to be efficient in the cross-coupling of aryl iodides under mild conditions.

AB - A novel magnetic composite catalyst has been prepared by immobilizing a palladium(0) complex, Pd2(dba)3, onto Mg-Al-layered double hydroxide shell supported on magnetite core. This new catalyst was characterized by XRD, TEM, EDX, FTIR, XPS, thermogravimetry and microanalytical techniques and magnetometric measurements. The performance of the catalyst was tested in the Heck and Suzuki reactions and confirmed to be efficient in the cross-coupling of aryl iodides under mild conditions.

KW - Core-shell

KW - Heck and Suzuki reactions

KW - Heterogeneous catalyst

KW - Layered double hydroxide

KW - Magnetic catalyst

KW - Palladium

UR - https://www.scopus.com/pages/publications/84868658994

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U2 - 10.1016/j.inoche.2012.10.020

DO - 10.1016/j.inoche.2012.10.020

M3 - Article

AN - SCOPUS:84868658994

SN - 1387-7003

VL - 27

SP - 64

EP - 68

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Magnetically-recoverable Pd-immobilized layered double hydroxide-iron oxide nanocomposite catalyst for carbon-carbon cross-coupling reactions

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