Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

Nurettin Baleioglu; Fatma Sevin; Ozden Ozel Evin; N. Bekir Peynircioglu

doi:10.1002/bbpc.19920960206

Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

Nurettin Baleioglu
, Fatma Sevin
, Ozden Ozel Evin
, N. Bekir Peynircioglu

Organik Kimya Anabilim Dalı

Hacettepe University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

1 Alıntı (Scopus)

Özet

Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	139-142
Sayfa sayısı	4
Dergi	Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
Hacim	96
Basın numarası	2
DOI'lar	https://doi.org/10.1002/bbpc.19920960206
Yayın durumu	Yayınlandı - 1992

Belgeye Erişim

10.1002/bbpc.19920960206

Diger dosyalar ve linkler

Link to publication in Scopus

Bundan alıntı yap

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title = "Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers",

abstract = "Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.",

author = "Nurettin Baleioglu and Fatma Sevin and Evin, \{Ozden Ozel\} and Peynircioglu, \{N. Bekir\}",

year = "1992",

doi = "10.1002/bbpc.19920960206",

language = "English",

volume = "96",

pages = "139--142",

journal = "Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics",

issn = "0005-9021",

publisher = "VCH Publishers",

number = "2",

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TY - JOUR

T1 - Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

AU - Baleioglu, Nurettin

AU - Sevin, Fatma

AU - Evin, Ozden Ozel

AU - Peynircioglu, N. Bekir

PY - 1992

Y1 - 1992

N2 - Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

AB - Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

UR - https://www.scopus.com/pages/publications/0026813517

U2 - 10.1002/bbpc.19920960206

DO - 10.1002/bbpc.19920960206

M3 - Article

AN - SCOPUS:0026813517

SN - 0005-9021

VL - 96

SP - 139

EP - 142

JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

IS - 2

ER -

Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

Özet

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