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Diaquabis(2-bromo-benzoato-κO)bis-(N,N-diethyl-nicotinamide-κN 1)zinc(II)

  • Tuncer Hökelek
  • , Hakan Dal
  • , Bariş Tercan
  • , F. Elif Özbek
  • , Hacali Necefoǧlu
  • Anadolu University
  • Karabuk University
  • Kafkas University

Araştırma sonucu: Dergiye katkıMakalebilirkişi

10 Alıntılar (Scopus)

Özet

In the centrosymmetric title complex, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], the ZnII atom is located on an inversion center. The asymmetric unit contains one 2-bromo-benzoate (BB), one diethyl-nicotinamide (DENA) ligand and one coordinating water molecule. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 85.51 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 44.07 (6)°. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains.

Orijinal dilİngilizce
Sayfa (başlangıç-bitiş)m481-m482
DergiActa Crystallographica Section E: Structure Reports Online
Hacim65
Basın numarası5
DOI'lar
Yayın durumuYayınlandı - 2009

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