Bis(4-fluorobenzoato-κ2 O,O′)bis-(nicotinamide- κN 1)zinc(II) monohydrate

Tuncer Hökelek; Nagihan Caylak; Hacali Necefoǧlu

doi:10.1107/S1600536808003747

Bis(4-fluorobenzoato-κ² O,O′)bis-(nicotinamide- κN ¹)zinc(II) monohydrate

Tuncer Hökelek
, Nagihan Caylak
, Hacali Necefoǧlu

Hacettepe Üniversitesi

Sakarya University
Kafkas University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

3 Alıntılar (Scopus)

Özet

The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the Zn^II atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	m460-m461
Dergi	Acta Crystallographica Section E: Structure Reports Online
Hacim	64
Basın numarası	3
DOI'lar	https://doi.org/10.1107/S1600536808003747
Yayın durumu	Yayınlandı - 2008

Belgeye Erişim

10.1107/S1600536808003747

Diger dosyalar ve linkler

Link to publication in Scopus

Bundan alıntı yap

@article{a56ff7319e284b07950eaa55d7895980,

title = "Bis(4-fluorobenzoato-κ2 O,O′)bis-(nicotinamide- κN 1)zinc(II) monohydrate",

abstract = "The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the ZnII atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure.",

author = "Tuncer H{\"o}kelek and Nagihan Caylak and Hacali Necefoǧlu",

year = "2008",

doi = "10.1107/S1600536808003747",

language = "English",

volume = "64",

pages = "m460--m461",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

}

TY - JOUR

T1 - Bis(4-fluorobenzoato-κ2 O,O′)bis-(nicotinamide- κN 1)zinc(II) monohydrate

AU - Hökelek, Tuncer

AU - Caylak, Nagihan

AU - Necefoǧlu, Hacali

PY - 2008

Y1 - 2008

N2 - The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the ZnII atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure.

AB - The title compound, [Zn(C7H4FO2)2(C6H6N2O)2]·H2O, is a monomeric complex. It contains two 4-fluoro-benzoate and two nicotinamide ligands and one uncoordinated water mol-ecule. The 4-fluoro-benzoates act as bidentate chelating ligands, while the nicotinamides are monodentate. The six-coordinate geometry around the ZnII atom may be described as highly distorted octa-hedral, with the two nicotinamide ligands arranged cis. Inter-molecular O - H⋯O and N - H⋯O hydrogen bonds link the mol-ecules into a supra-molecular structure.

UR - https://www.scopus.com/pages/publications/40249118486

U2 - 10.1107/S1600536808003747

DO - 10.1107/S1600536808003747

M3 - Article

AN - SCOPUS:40249118486

SN - 1600-5368

VL - 64

SP - m460-m461

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3