An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

D. Gürçay; Z. Kantarci; S. Aydin

doi:10.1016/S0022-2860(98)00838-2

An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

D. Gürçay
, Z. Kantarci
, S. Aydin

Gazi University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

Özet

Evidence based on the IR and Raman spectral features of Hg(CN)₂ in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

Orijinal dil	İngilizce
Sayfa (başlangıç-bitiş)	65-68
Sayfa sayısı	4
Dergi	Journal of Molecular Structure
Hacim	482-483
DOI'lar	https://doi.org/10.1016/S0022-2860(98)00838-2
Yayın durumu	Yayınlandı - 25 May 1999
Harici olarak yayınlandı	Evet

Belgeye Erişim

10.1016/S0022-2860(98)00838-2

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Link to publication in Scopus

Bundan alıntı yap

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title = "An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents",

abstract = "Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.",

keywords = "Infrared spectra, Mercuric cyanide, Raman spectra, Solute-solvent interactions, Solution chemistry",

author = "D. G{\"u}r{\c c}ay and Z. Kantarci and S. Aydin",

year = "1999",

month = may,

day = "25",

doi = "10.1016/S0022-2860(98)00838-2",

language = "English",

volume = "482-483",

pages = "65--68",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

AU - Gürçay, D.

AU - Kantarci, Z.

AU - Aydin, S.

PY - 1999/5/25

Y1 - 1999/5/25

N2 - Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

AB - Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

KW - Infrared spectra

KW - Mercuric cyanide

KW - Raman spectra

KW - Solute-solvent interactions

KW - Solution chemistry

UR - https://www.scopus.com/pages/publications/0345465615

U2 - 10.1016/S0022-2860(98)00838-2

DO - 10.1016/S0022-2860(98)00838-2

M3 - Article

AN - SCOPUS:0345465615

SN - 0022-2860

VL - 482-483

SP - 65

EP - 68

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

Özet

Belgeye Erişim

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