1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Firudin I. Guseinov; Aida I. Samigullina; Tuncer Hökelek; Sahil Z. Hamidov; Jamal Lasri; Khudayar I. Hasanov; Tahir A. Javadzade; Alebel N. Belay

doi:10.1107/S2414314625004663

1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Firudin I. Guseinov
, Aida I. Samigullina
, Tuncer Hökelek
, Sahil Z. Hamidov
, Jamal Lasri
, Khudayar I. Hasanov
, Tahir A. Javadzade
, Alebel N. Belay

Hacettepe Üniversitesi

Moscow State University of Design and Technology
Russian Academy of Sciences
Azerbaijan Technological University
King Abdulaziz University
Western Caspian University
Azerbaycan Tibb Universiteti
Khazar University
Bahar Dar University

Araştırma sonucu: Dergiye katkı › Makale › bilirkişi

Özet

In the title compound, 0.638C₂₃H₁₆BrF₃N₂·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

Orijinal dil	İngilizce
Makale numarası	x250466
Sayfa (başlangıç-bitiş)	x250466
Dergi	IUCrData
Hacim	10
Basın numarası	Pt 6
DOI'lar	https://doi.org/10.1107/S2414314625004663
Yayın durumu	Yayınlandı - 1 Haz 2025

Belgeye Erişim

10.1107/S2414314625004663

Diger dosyalar ve linkler

Link to publication in Scopus

Bundan alıntı yap

@article{ee26c842e80c42dc906849e4aed2012e,

title = "1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)",

abstract = "In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1\%), H⋯F/F⋯H (21.4\%) and H⋯C/C⋯H (18.9\%) interactions.",

keywords = "crystal structure, hydrogen bond, pyrazole",

author = "Guseinov, \{Firudin I.\} and Samigullina, \{Aida I.\} and Tuncer H{\"o}kelek and Hamidov, \{Sahil Z.\} and Jamal Lasri and Hasanov, \{Khudayar I.\} and Javadzade, \{Tahir A.\} and Belay, \{Alebel N.\}",

note = "Publisher Copyright: {\textcopyright} Guseinov et al. 2025.",

year = "2025",

month = jun,

day = "1",

doi = "10.1107/S2414314625004663",

language = "English",

volume = "10",

pages = "x250466",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

number = "Pt 6",

}

TY - JOUR

T1 - 1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

AU - Guseinov, Firudin I.

AU - Samigullina, Aida I.

AU - Hökelek, Tuncer

AU - Hamidov, Sahil Z.

AU - Lasri, Jamal

AU - Hasanov, Khudayar I.

AU - Javadzade, Tahir A.

AU - Belay, Alebel N.

N1 - Publisher Copyright: © Guseinov et al. 2025.

PY - 2025/6/1

Y1 - 2025/6/1

N2 - In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

AB - In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

KW - crystal structure

KW - hydrogen bond

KW - pyrazole

UR - https://www.scopus.com/pages/publications/105010600489

U2 - 10.1107/S2414314625004663

DO - 10.1107/S2414314625004663

M3 - Article

C2 - 40630054

AN - SCOPUS:105010600489

SN - 2414-3146

VL - 10

SP - x250466

JO - IUCrData

JF - IUCrData

IS - Pt 6

M1 - x250466

ER -

1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Özet

Belgeye Erişim

Diger dosyalar ve linkler

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