Vibrational spectroscopic study of 1H-1,2,4-triazole hofmann-T d-type complexes

Celal Bayrak

Vibrational spectroscopic study of 1H-1,2,4-triazole hofmann-T _d-type complexes

Celal Bayrak

Division of Physics Teaching

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Abstract

Hofmann-T_d-type modified hosts containing 1H-1,2,4-triazole molecule attached to M(II) tetracyanocadmate frame, with a given formula: M(Htrz)₂M'(CN)₄, where M = Mn; M' = Zn, Cd or Hg; M = Cd, M' = Cd or Hg; Htrz = 1H-1,2,4-triazole, have been synthesized. Their elemental analyses, FT-IR (4000-400 cm^-1) and the FT-Raman spectra (4000-50 cm^-1) are reported for the two [Cd(Htrz)2Cd(CN)₄ and Cd(Htrz)₂Hg(CN)₄] of these complexes. All the vibrational modes of coordinated Htrz are characterised. The spectral features of the compounds studied are found to be similar to each other indicating that they have analogous structures.

Original language	English
Pages (from-to)	1201-1204
Number of pages	4
Journal	Asian Journal of Chemistry
Volume	23
Issue number	3
Publication status	Published - 2011

Keywords

1H-1,2,4-Triazole
FT-IR and FT-Raman spectra

Cite this

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title = "Vibrational spectroscopic study of 1H-1,2,4-triazole hofmann-T d-type complexes",

abstract = "Hofmann-Td-type modified hosts containing 1H-1,2,4-triazole molecule attached to M(II) tetracyanocadmate frame, with a given formula: M(Htrz)2M'(CN)4, where M = Mn; M' = Zn, Cd or Hg; M = Cd, M' = Cd or Hg; Htrz = 1H-1,2,4-triazole, have been synthesized. Their elemental analyses, FT-IR (4000-400 cm-1) and the FT-Raman spectra (4000-50 cm-1) are reported for the two [Cd(Htrz)2Cd(CN)4 and Cd(Htrz)2Hg(CN)4] of these complexes. All the vibrational modes of coordinated Htrz are characterised. The spectral features of the compounds studied are found to be similar to each other indicating that they have analogous structures.",

keywords = "1H-1,2,4-Triazole, FT-IR and FT-Raman spectra",

author = "Celal Bayrak",

year = "2011",

language = "English",

volume = "23",

pages = "1201--1204",

journal = "Asian Journal of Chemistry",

issn = "0970-7077",

publisher = "Asian Publication Corporation",

number = "3",

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TY - JOUR

T1 - Vibrational spectroscopic study of 1H-1,2,4-triazole hofmann-T d-type complexes

AU - Bayrak, Celal

PY - 2011

Y1 - 2011

N2 - Hofmann-Td-type modified hosts containing 1H-1,2,4-triazole molecule attached to M(II) tetracyanocadmate frame, with a given formula: M(Htrz)2M'(CN)4, where M = Mn; M' = Zn, Cd or Hg; M = Cd, M' = Cd or Hg; Htrz = 1H-1,2,4-triazole, have been synthesized. Their elemental analyses, FT-IR (4000-400 cm-1) and the FT-Raman spectra (4000-50 cm-1) are reported for the two [Cd(Htrz)2Cd(CN)4 and Cd(Htrz)2Hg(CN)4] of these complexes. All the vibrational modes of coordinated Htrz are characterised. The spectral features of the compounds studied are found to be similar to each other indicating that they have analogous structures.

AB - Hofmann-Td-type modified hosts containing 1H-1,2,4-triazole molecule attached to M(II) tetracyanocadmate frame, with a given formula: M(Htrz)2M'(CN)4, where M = Mn; M' = Zn, Cd or Hg; M = Cd, M' = Cd or Hg; Htrz = 1H-1,2,4-triazole, have been synthesized. Their elemental analyses, FT-IR (4000-400 cm-1) and the FT-Raman spectra (4000-50 cm-1) are reported for the two [Cd(Htrz)2Cd(CN)4 and Cd(Htrz)2Hg(CN)4] of these complexes. All the vibrational modes of coordinated Htrz are characterised. The spectral features of the compounds studied are found to be similar to each other indicating that they have analogous structures.

KW - 1H-1,2,4-Triazole

KW - FT-IR and FT-Raman spectra

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M3 - Article

AN - SCOPUS:79951832366

SN - 0970-7077

VL - 23

SP - 1201

EP - 1204

JO - Asian Journal of Chemistry

JF - Asian Journal of Chemistry

IS - 3

ER -

Vibrational spectroscopic study of 1H-1,2,4-triazole hofmann-T _d-type complexes

Abstract

Keywords

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