Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

Fatma Sevin; Ikay Sökmen; Bülent Düz; Philip B. Shevlin

doi:10.1016/S0040-4039(03)00579-3

Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

Fatma Sevin
, Ikay Sökmen
, Bülent Düz
, Philip B. Shevlin

Hacettepe University
Auburn University

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.

Original language	English
Pages (from-to)	3405-3407
Number of pages	3
Journal	Tetrahedron Letters
Volume	44
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4039(03)00579-3
Publication status	Published - 14 Apr 2003

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abstract = "Reaction of atomic carbon with phenol generates tropone in a reaction postulated to proceed via the hydroxycycloheptatetraenes, which rearrange to tropone. When the hydroxyphenylcarbenes are generated by the C atom deoxygenation of the corresponding aldehydes, the meta and para isomers produce tropone; the ortho isomer does not.",

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Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol

Abstract

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