The novel sensitive and selective chemosensors for determination of multiple analytes

Deniz Çakmaz; Arda Özarslan; Burcu Aydıner; Ahmet Burak Eroğlu; Nurgül Seferoğlu; Hülya Şenöz; Zeynel Seferoğlu

doi:10.1016/j.dyepig.2020.108701

The novel sensitive and selective chemosensors for determination of multiple analytes

Deniz Çakmaz
, Arda Özarslan
, Burcu Aydıner
, Ahmet Burak Eroğlu
, Nurgül Seferoğlu
, Hülya Şenöz
, Zeynel Seferoğlu

Division of Organic Chemistry (Science, Faculty of Science and Literature, Faculty of Basic Sciences)

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

Novel chemosensors that are azo dyes bearing coumarin with indole and thiophene recognition moieties were synthesized. Sensor properties of the dyes were investigated within multiple basic environments that include various pH ranges, anions, and organic amines. Recognition of the basic media by the chemosensors that have acidic NH and NH₂ groups, occurs via the deprotonation process which was supported with reversibility study and ¹H NMR experiments. The Density Functional Theory calculations have employed to support the experimental results. Chemosensors 6a and 6b showed remarkable detection ability in a pH range of 7–11 and they have been also successfully utilized in the determination of CN⁻ in semi-aqueous media.

Original language	English
Article number	108701
Journal	Dyes and Pigments
Volume	183
DOIs	https://doi.org/10.1016/j.dyepig.2020.108701
Publication status	Published - Dec 2020

Keywords

Anions
Azo dyes
Colorimetric chemosensors
DFT
Organic bases
pH sensors

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10.1016/j.dyepig.2020.108701

Cite this

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title = "The novel sensitive and selective chemosensors for determination of multiple analytes",

abstract = "Novel chemosensors that are azo dyes bearing coumarin with indole and thiophene recognition moieties were synthesized. Sensor properties of the dyes were investigated within multiple basic environments that include various pH ranges, anions, and organic amines. Recognition of the basic media by the chemosensors that have acidic NH and NH2 groups, occurs via the deprotonation process which was supported with reversibility study and 1H NMR experiments. The Density Functional Theory calculations have employed to support the experimental results. Chemosensors 6a and 6b showed remarkable detection ability in a pH range of 7–11 and they have been also successfully utilized in the determination of CN− in semi-aqueous media.",

keywords = "Anions, Azo dyes, Colorimetric chemosensors, DFT, Organic bases, pH sensors",

author = "Deniz {\c C}akmaz and Arda {\"O}zarslan and Burcu Aydıner and Eroğlu, \{Ahmet Burak\} and Nurg{\"u}l Seferoğlu and H{\"u}lya {\c S}en{\"o}z and Zeynel Seferoğlu",

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year = "2020",

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doi = "10.1016/j.dyepig.2020.108701",

language = "English",

volume = "183",

journal = "Dyes and Pigments",

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T1 - The novel sensitive and selective chemosensors for determination of multiple analytes

AU - Çakmaz, Deniz

AU - Özarslan, Arda

AU - Aydıner, Burcu

AU - Eroğlu, Ahmet Burak

AU - Seferoğlu, Nurgül

AU - Şenöz, Hülya

AU - Seferoğlu, Zeynel

PY - 2020/12

Y1 - 2020/12

N2 - Novel chemosensors that are azo dyes bearing coumarin with indole and thiophene recognition moieties were synthesized. Sensor properties of the dyes were investigated within multiple basic environments that include various pH ranges, anions, and organic amines. Recognition of the basic media by the chemosensors that have acidic NH and NH2 groups, occurs via the deprotonation process which was supported with reversibility study and 1H NMR experiments. The Density Functional Theory calculations have employed to support the experimental results. Chemosensors 6a and 6b showed remarkable detection ability in a pH range of 7–11 and they have been also successfully utilized in the determination of CN− in semi-aqueous media.

AB - Novel chemosensors that are azo dyes bearing coumarin with indole and thiophene recognition moieties were synthesized. Sensor properties of the dyes were investigated within multiple basic environments that include various pH ranges, anions, and organic amines. Recognition of the basic media by the chemosensors that have acidic NH and NH2 groups, occurs via the deprotonation process which was supported with reversibility study and 1H NMR experiments. The Density Functional Theory calculations have employed to support the experimental results. Chemosensors 6a and 6b showed remarkable detection ability in a pH range of 7–11 and they have been also successfully utilized in the determination of CN− in semi-aqueous media.

KW - Anions

KW - Azo dyes

KW - Colorimetric chemosensors

KW - DFT

KW - Organic bases

KW - pH sensors

UR - https://www.scopus.com/pages/publications/85089529998

U2 - 10.1016/j.dyepig.2020.108701

DO - 10.1016/j.dyepig.2020.108701

M3 - Article

AN - SCOPUS:85089529998

SN - 0143-7208

VL - 183

JO - Dyes and Pigments

JF - Dyes and Pigments

M1 - 108701

ER -

The novel sensitive and selective chemosensors for determination of multiple analytes

Abstract

Keywords

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