The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

E. Kendi; D. Ülkü

doi:10.1524/zkri.1976.144.1-6.91

The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

E. Kendi
, D. Ülkü

Hacettepe University

Hacettepe University

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

Original language	English
Pages (from-to)	91-96
Number of pages	6
Journal	Zeitschrift fur Kristallographie - New Crystal Structures
Volume	144
Issue number	1-6
DOIs	https://doi.org/10.1524/zkri.1976.144.1-6.91
Publication status	Published - 1976

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10.1524/zkri.1976.144.1-6.91

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title = "The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2",

abstract = "The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) {\AA}, c = 8.082(6) {\AA}; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.",

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doi = "10.1524/zkri.1976.144.1-6.91",

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T1 - The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

AU - Kendi, E.

AU - Ülkü, D.

PY - 1976

Y1 - 1976

N2 - The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

AB - The crystal structure of diammin-cadmium tetracyanonickelate di-dioxane was determined from Weissenberg data. The crystals are tetragonal, space group P4/m with unit-cell dimensions a = 7.586(9) Å, c = 8.082(6) Å; the cell contains one formula unit. The parameters obtained from Fourier synthesis were least-squares refined to an B value of 0.11. The structure is a new member of Hofmann-type clathrates with the general formula M(NH3)2 · Ni(CN)4 · 2G. The guest molecule G in this unstable compound is a non-aromatic one.

UR - https://www.scopus.com/pages/publications/84942960467

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JO - Zeitschrift fur Kristallographie - New Crystal Structures

JF - Zeitschrift fur Kristallographie - New Crystal Structures

IS - 1-6

ER -

The crystal structure of cadmium-nickel dioxane clathrate Cd(NH3)2 · Ni(CN)4 · 2C4H8O2

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