Synthesis, molecular structure, optical properties and electrical conductivity of zwitterionic ferrocenyldithiophosphonates

Mehmet Karakus; Yildirum Aydogdu; Omer Celik; Veysel Kuzucu; Semra Ide; Evamarie Hey-Hawkins

doi:10.1002/zaac.200600319

Synthesis, molecular structure, optical properties and electrical conductivity of zwitterionic ferrocenyldithiophosphonates

Mehmet Karakus
, Yildirum Aydogdu
, Omer Celik
, Veysel Kuzucu
, Semra Ide
, Evamarie Hey-Hawkins

Division of General Physics

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

Ferrocenyldithiodiphosphetane [FcPS(μ-S)]₂ [Fc = Fe(η⁵-C₅H₄)(η⁵-C ₅H₅)] reacts with the aminoethanol derivatives 11-ethyl-3-pyrrolidinol and 2-(piperazin-1-yl)ethanol to give the zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates [FcP(S)S(OC₄H ₇NHEt)] (2) and [FcP(S)S(OC₂H₄NHC ₄H₈NH)] (3), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electri-cal properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC₂H₄NHEt₂)] (1) were studied. A molecular structure determination of 1 is also reported.

Original language	English
Pages (from-to)	405-410
Number of pages	6
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	633
Issue number	3
DOIs	https://doi.org/10.1002/zaac.200600319
Publication status	Published - 2007

Keywords

Conductivity
Molecular structure
Optical properties
Zwitterionic ferrocenyldithiophosphonates

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10.1002/zaac.200600319

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@article{3ac533870bc74cf7848c6f682201f298,

title = "Synthesis, molecular structure, optical properties and electrical conductivity of zwitterionic ferrocenyldithiophosphonates",

abstract = "Ferrocenyldithiodiphosphetane [FcPS(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C 5H5)] reacts with the aminoethanol derivatives 11-ethyl-3-pyrrolidinol and 2-(piperazin-1-yl)ethanol to give the zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates [FcP(S)S(OC4H 7NHEt)] (2) and [FcP(S)S(OC2H4NHC 4H8NH)] (3), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electri-cal properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC2H4NHEt2)] (1) were studied. A molecular structure determination of 1 is also reported.",

keywords = "Conductivity, Molecular structure, Optical properties, Zwitterionic ferrocenyldithiophosphonates",

author = "Mehmet Karakus and Yildirum Aydogdu and Omer Celik and Veysel Kuzucu and Semra Ide and Evamarie Hey-Hawkins",

year = "2007",

doi = "10.1002/zaac.200600319",

language = "English",

volume = "633",

pages = "405--410",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "Wiley-VCH Verlag",

number = "3",

}

TY - JOUR

T1 - Synthesis, molecular structure, optical properties and electrical conductivity of zwitterionic ferrocenyldithiophosphonates

AU - Karakus, Mehmet

AU - Aydogdu, Yildirum

AU - Celik, Omer

AU - Kuzucu, Veysel

AU - Ide, Semra

AU - Hey-Hawkins, Evamarie

PY - 2007

Y1 - 2007

N2 - Ferrocenyldithiodiphosphetane [FcPS(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C 5H5)] reacts with the aminoethanol derivatives 11-ethyl-3-pyrrolidinol and 2-(piperazin-1-yl)ethanol to give the zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates [FcP(S)S(OC4H 7NHEt)] (2) and [FcP(S)S(OC2H4NHC 4H8NH)] (3), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electri-cal properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC2H4NHEt2)] (1) were studied. A molecular structure determination of 1 is also reported.

AB - Ferrocenyldithiodiphosphetane [FcPS(μ-S)]2 [Fc = Fe(η5-C5H4)(η5-C 5H5)] reacts with the aminoethanol derivatives 11-ethyl-3-pyrrolidinol and 2-(piperazin-1-yl)ethanol to give the zwitterionic (O-ethylammonium)ferrocenyldithiophosphonates [FcP(S)S(OC4H 7NHEt)] (2) and [FcP(S)S(OC2H4NHC 4H8NH)] (3), which were fully characterized by elemental analysis, IR and NMR spectroscopy and mass spectrometry. The optical and electri-cal properties of 2 and 3 as well as those of the previously reported [FcP(S)S(OC2H4NHEt2)] (1) were studied. A molecular structure determination of 1 is also reported.

KW - Conductivity

KW - Molecular structure

KW - Optical properties

KW - Zwitterionic ferrocenyldithiophosphonates

UR - https://www.scopus.com/pages/publications/33847320244

U2 - 10.1002/zaac.200600319

DO - 10.1002/zaac.200600319

M3 - Article

AN - SCOPUS:33847320244

SN - 0044-2313

VL - 633

SP - 405

EP - 410

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 3

ER -

Synthesis, molecular structure, optical properties and electrical conductivity of zwitterionic ferrocenyldithiophosphonates

Abstract

Keywords

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