Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors

Nurşen Altuntaş Öztaş; Gülgün Yenişehirli; Nilgün Ancin; Selma Gül Öztaş; Yusuf Özcan; Semra Ide

doi:10.1016/j.saa.2008.12.023

Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors

Nurşen Altuntaş Öztaş
, Gülgün Yenişehirli
, Nilgün Ancin
, Selma Gül Öztaş
, Yusuf Özcan
, Semra Ide

Gaziosmanpasa University
Ankara University
Hacettepe University

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

Four different dimethyltin(IV) complexes of Schiff bases derived from 2-amino-3-hydroxypyridine and different substituted salicylaldehydes have been synthesized. The compounds, with the general formula [Me₂Sn(2-OArCH{double bond, long}NC₅H₃NO)], where Ar = -C₆H₃(5-CH₃) [Me₂SnL¹], -C₆H₃(5-NO₂) [Me₂SnL²], -C₆H₂(3,5-Cl₂) [Me₂SnL³], and -C₆H₂(3,5-I₂) [Me₂SnL⁴], were characterized by IR, NMR (¹H and ¹³C), mass spectroscopy and elemental analysis. Me₂SnL³ was also characterized by X-ray diffraction analysis and shows a fivefold C₂NO₂ coordination with distorted square pyramidal geometry. H₃C-Sn-CH₃ angles in the complexes were calculated using Lockhart's equations with the ¹J(^117/119Sn-¹³C) and ²J(^117/119Sn-¹H) values (from the ¹H-NMR and ¹³C-NMR spectra). The in vitro antibacterial and antifungal activities of dimethyltin(IV) complexes were also investigated.

Original language	English
Pages (from-to)	929-935
Number of pages	7
Journal	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy
Volume	72
Issue number	5
DOIs	https://doi.org/10.1016/j.saa.2008.12.023
Publication status	Published - Jun 2009

Keywords

Antibacterial
Antifungal
Crystal structure
Diorganotin(IV)
Schiff base

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10.1016/j.saa.2008.12.023

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@article{75ff15e29928425499529e816221914b,

title = "Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors",

abstract = "Four different dimethyltin(IV) complexes of Schiff bases derived from 2-amino-3-hydroxypyridine and different substituted salicylaldehydes have been synthesized. The compounds, with the general formula [Me2Sn(2-OArCH\{double bond, long\}NC5H3NO)], where Ar = -C6H3(5-CH3) [Me2SnL1], -C6H3(5-NO2) [Me2SnL2], -C6H2(3,5-Cl2) [Me2SnL3], and -C6H2(3,5-I2) [Me2SnL4], were characterized by IR, NMR (1H and 13C), mass spectroscopy and elemental analysis. Me2SnL3 was also characterized by X-ray diffraction analysis and shows a fivefold C2NO2 coordination with distorted square pyramidal geometry. H3C-Sn-CH3 angles in the complexes were calculated using Lockhart's equations with the 1J(117/119Sn-13C) and 2J(117/119Sn-1H) values (from the 1H-NMR and 13C-NMR spectra). The in vitro antibacterial and antifungal activities of dimethyltin(IV) complexes were also investigated.",

keywords = "Antibacterial, Antifungal, Crystal structure, Diorganotin(IV), Schiff base",

author = "{\"O}zta{\c s}, \{Nur{\c s}en Altunta{\c s}\} and G{\"u}lg{\"u}n Yeni{\c s}ehirli and Nilg{\"u}n Ancin and {\"O}zta{\c s}, \{Selma G{\"u}l\} and Yusuf {\"O}zcan and Semra Ide",

year = "2009",

month = jun,

doi = "10.1016/j.saa.2008.12.023",

language = "English",

volume = "72",

pages = "929--935",

journal = "Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy",

issn = "1386-1425",

publisher = "Elsevier B.V.",

number = "5",

}

Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors. / Öztaş, Nurşen Altuntaş; Yenişehirli, Gülgün; Ancin, Nilgün et al.
In: Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, Vol. 72, No. 5, 06.2009, p. 929-935.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors

AU - Öztaş, Nurşen Altuntaş

AU - Yenişehirli, Gülgün

AU - Ancin, Nilgün

AU - Öztaş, Selma Gül

AU - Özcan, Yusuf

AU - Ide, Semra

PY - 2009/6

Y1 - 2009/6

N2 - Four different dimethyltin(IV) complexes of Schiff bases derived from 2-amino-3-hydroxypyridine and different substituted salicylaldehydes have been synthesized. The compounds, with the general formula [Me2Sn(2-OArCH{double bond, long}NC5H3NO)], where Ar = -C6H3(5-CH3) [Me2SnL1], -C6H3(5-NO2) [Me2SnL2], -C6H2(3,5-Cl2) [Me2SnL3], and -C6H2(3,5-I2) [Me2SnL4], were characterized by IR, NMR (1H and 13C), mass spectroscopy and elemental analysis. Me2SnL3 was also characterized by X-ray diffraction analysis and shows a fivefold C2NO2 coordination with distorted square pyramidal geometry. H3C-Sn-CH3 angles in the complexes were calculated using Lockhart's equations with the 1J(117/119Sn-13C) and 2J(117/119Sn-1H) values (from the 1H-NMR and 13C-NMR spectra). The in vitro antibacterial and antifungal activities of dimethyltin(IV) complexes were also investigated.

AB - Four different dimethyltin(IV) complexes of Schiff bases derived from 2-amino-3-hydroxypyridine and different substituted salicylaldehydes have been synthesized. The compounds, with the general formula [Me2Sn(2-OArCH{double bond, long}NC5H3NO)], where Ar = -C6H3(5-CH3) [Me2SnL1], -C6H3(5-NO2) [Me2SnL2], -C6H2(3,5-Cl2) [Me2SnL3], and -C6H2(3,5-I2) [Me2SnL4], were characterized by IR, NMR (1H and 13C), mass spectroscopy and elemental analysis. Me2SnL3 was also characterized by X-ray diffraction analysis and shows a fivefold C2NO2 coordination with distorted square pyramidal geometry. H3C-Sn-CH3 angles in the complexes were calculated using Lockhart's equations with the 1J(117/119Sn-13C) and 2J(117/119Sn-1H) values (from the 1H-NMR and 13C-NMR spectra). The in vitro antibacterial and antifungal activities of dimethyltin(IV) complexes were also investigated.

KW - Antibacterial

KW - Antifungal

KW - Crystal structure

KW - Diorganotin(IV)

KW - Schiff base

UR - https://www.scopus.com/pages/publications/61649100050

U2 - 10.1016/j.saa.2008.12.023

DO - 10.1016/j.saa.2008.12.023

M3 - Article

C2 - 19185533

AN - SCOPUS:61649100050

SN - 1386-1425

VL - 72

SP - 929

EP - 935

JO - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

JF - Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

IS - 5

ER -

Synthesis, characterization, biological activities of dimethyltin(IV) complexes of Schiff bases with ONO-type donors

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