Poly[(μ5-2,2′-bipyridine-5,5′-dicarboxylato) lead(II)]

Mustafa Sertçelik; Nagihan Çaylak Delibaş; Sabri Çevik; Hacali Necefoǧlu; Tuncer Hökelek

doi:10.1107/S1600536812035647

Poly[(μ₅-2,2′-bipyridine-5,5′-dicarboxylato) lead(II)]

Mustafa Sertçelik
, Nagihan Çaylak Delibaş
, Sabri Çevik
, Hacali Necefoǧlu
, Tuncer Hökelek

Hacettepe University

Kafkas University
Sakarya University
Afyon Kocatepe University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title polymeric compound, [Pb(C₁₂H₆N ₂O₄)]_n, the Pb^II cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′- dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N₂O₆ geometry. The carboxylate groups bridge the Pb^II cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.

Original language	English
Pages (from-to)	m1196-m1197
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	9
DOIs	https://doi.org/10.1107/S1600536812035647
Publication status	Published - Sept 2012

Access to Document

10.1107/S1600536812035647

Cite this

@article{dde74a5cabe24c02a7f9d0b7f1b112ba,

title = "Poly[(μ5-2,2′-bipyridine-5,5′-dicarboxylato) lead(II)]",

abstract = "In the title polymeric compound, [Pb(C12H6N 2O4)]n, the PbII cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′- dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.",

author = "Mustafa Sert{\c c}elik and \{{\c C}aylak Deliba{\c s}\}, Nagihan and Sabri {\c C}evik and Hacali Necefoǧlu and Tuncer H{\"o}kelek",

year = "2012",

month = sep,

doi = "10.1107/S1600536812035647",

language = "English",

volume = "68",

pages = "m1196--m1197",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "9",

}

TY - JOUR

T1 - Poly[(μ5-2,2′-bipyridine-5,5′-dicarboxylato) lead(II)]

AU - Sertçelik, Mustafa

AU - Çaylak Delibaş, Nagihan

AU - Çevik, Sabri

AU - Necefoǧlu, Hacali

AU - Hökelek, Tuncer

PY - 2012/9

Y1 - 2012/9

N2 - In the title polymeric compound, [Pb(C12H6N 2O4)]n, the PbII cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′- dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.

AB - In the title polymeric compound, [Pb(C12H6N 2O4)]n, the PbII cation, located on a mirror plane, is N,N′-chelated by a 2-2′-bipyridine-5,5′- dicarboxylate (bpdc) anion and is further coordinated by six O atoms from four carboxyl groups of bpdc anions in an irregular N2O6 geometry. The carboxylate groups bridge the PbII cations, forming a three-dimensional polymeric structure. The carboxylate group is twisted away from the attached pyridine ring by 11.4 (3)°.

UR - https://www.scopus.com/pages/publications/84865795609

U2 - 10.1107/S1600536812035647

DO - 10.1107/S1600536812035647

M3 - Article

C2 - 22969486

AN - SCOPUS:84865795609

SN - 1600-5368

VL - 68

SP - m1196-m1197

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 9

ER -

Poly[(μ₅-2,2′-bipyridine-5,5′-dicarboxylato) lead(II)]

Abstract

Access to Document

Other files and links

Fingerprint

Cite this