Micellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scattering

Y. Özcan; S. Ide; U. Jeng; V. Bütün; Y. H. Lai; C. H. Su

doi:10.1016/j.matchemphys.2012.12.019

Micellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scattering

Y. Özcan
, S. Ide
, U. Jeng
, V. Bütün
, Y. H. Lai
, C. H. Su

Division of General Physics

Pamukkale University
National Synchrotron Radiation Research Center Taiwan
National Tsing Hua University
Osmangazi University
Tunghai University
Industrial Technology Research Institute of Taiwan

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

We have studied the micellization behavior of tertiary amine methacrylate-based diblock copolymers, comprising the hydrophobic poly[2-(diethylamino)ethyl methacrylate] (PDEA) and hydrophilic/polyelectrolyte poly[2-(dimethylamino)ethyl methacrylate] (PDMA) blocks. Revealed by small-angle X-ray scattering (SAXS) and dynamics light scattering, micelle size of the PDMA_m-b-PDEA_n diblock copolymer in aqueous solution depends sensitively on the comonomer ratio n/m, molecular weight M_w, solution temperature, and solution pH values. Aggregation number is found to follow an empirical relation of N (n/m)^1.6, disregarding the molecular mass. With n/m = 0.5, M_w ≈ 12,000, and pH = 7.6, the diblock copolymer forms spherical core-shell micelles at 23 °C, with a PDEA-core radius of 52, a PDMA-shell thickness of 27, and an aggregation number of 127.

Original language	English
Pages (from-to)	559-564
Number of pages	6
Journal	Materials Chemistry and Physics
Volume	138
Issue number	2-3
DOIs	https://doi.org/10.1016/j.matchemphys.2012.12.019
Publication status	Published - 15 Mar 2013

Keywords

Chemical synthesis
Light scattering
Polymers
Small-angle scattering

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10.1016/j.matchemphys.2012.12.019

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title = "Micellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scattering",

abstract = "We have studied the micellization behavior of tertiary amine methacrylate-based diblock copolymers, comprising the hydrophobic poly[2-(diethylamino)ethyl methacrylate] (PDEA) and hydrophilic/polyelectrolyte poly[2-(dimethylamino)ethyl methacrylate] (PDMA) blocks. Revealed by small-angle X-ray scattering (SAXS) and dynamics light scattering, micelle size of the PDMAm-b-PDEAn diblock copolymer in aqueous solution depends sensitively on the comonomer ratio n/m, molecular weight Mw, solution temperature, and solution pH values. Aggregation number is found to follow an empirical relation of N (n/m)1.6, disregarding the molecular mass. With n/m = 0.5, Mw ≈ 12,000, and pH = 7.6, the diblock copolymer forms spherical core-shell micelles at 23 °C, with a PDEA-core radius of 52, a PDMA-shell thickness of 27, and an aggregation number of 127.",

keywords = "Chemical synthesis, Light scattering, Polymers, Small-angle scattering",

author = "Y. {\"O}zcan and S. Ide and U. Jeng and V. B{\"u}t{\"u}n and Lai, \{Y. H.\} and Su, \{C. H.\}",

year = "2013",

month = mar,

day = "15",

doi = "10.1016/j.matchemphys.2012.12.019",

language = "English",

volume = "138",

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T1 - Micellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scattering

AU - Özcan, Y.

AU - Ide, S.

AU - Jeng, U.

AU - Bütün, V.

AU - Lai, Y. H.

AU - Su, C. H.

PY - 2013/3/15

Y1 - 2013/3/15

N2 - We have studied the micellization behavior of tertiary amine methacrylate-based diblock copolymers, comprising the hydrophobic poly[2-(diethylamino)ethyl methacrylate] (PDEA) and hydrophilic/polyelectrolyte poly[2-(dimethylamino)ethyl methacrylate] (PDMA) blocks. Revealed by small-angle X-ray scattering (SAXS) and dynamics light scattering, micelle size of the PDMAm-b-PDEAn diblock copolymer in aqueous solution depends sensitively on the comonomer ratio n/m, molecular weight Mw, solution temperature, and solution pH values. Aggregation number is found to follow an empirical relation of N (n/m)1.6, disregarding the molecular mass. With n/m = 0.5, Mw ≈ 12,000, and pH = 7.6, the diblock copolymer forms spherical core-shell micelles at 23 °C, with a PDEA-core radius of 52, a PDMA-shell thickness of 27, and an aggregation number of 127.

AB - We have studied the micellization behavior of tertiary amine methacrylate-based diblock copolymers, comprising the hydrophobic poly[2-(diethylamino)ethyl methacrylate] (PDEA) and hydrophilic/polyelectrolyte poly[2-(dimethylamino)ethyl methacrylate] (PDMA) blocks. Revealed by small-angle X-ray scattering (SAXS) and dynamics light scattering, micelle size of the PDMAm-b-PDEAn diblock copolymer in aqueous solution depends sensitively on the comonomer ratio n/m, molecular weight Mw, solution temperature, and solution pH values. Aggregation number is found to follow an empirical relation of N (n/m)1.6, disregarding the molecular mass. With n/m = 0.5, Mw ≈ 12,000, and pH = 7.6, the diblock copolymer forms spherical core-shell micelles at 23 °C, with a PDEA-core radius of 52, a PDMA-shell thickness of 27, and an aggregation number of 127.

KW - Chemical synthesis

KW - Light scattering

KW - Polymers

KW - Small-angle scattering

UR - https://www.scopus.com/pages/publications/84874524099

U2 - 10.1016/j.matchemphys.2012.12.019

DO - 10.1016/j.matchemphys.2012.12.019

M3 - Article

AN - SCOPUS:84874524099

SN - 0254-0584

VL - 138

SP - 559

EP - 564

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 2-3

ER -

Micellization behavior of tertiary amine-methacrylate-based block copolymers characterized by small-angle X-ray scattering and dynamic light scattering

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Keywords

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