Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

Hanife Ibişoǧlu; Gönül Yenilmez Çiftçi; Adem Kiliç; Esra Tanriverdi; Ü N. Ilker; Dal Hakan; Tuncer Hökelek

doi:10.1007/s12039-009-0014-y

Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

Hanife Ibişoǧlu
, Gönül Yenilmez Çiftçi
, Adem Kiliç
, Esra Tanriverdi
, Ü N. Ilker
, Dal Hakan
, Tuncer Hökelek

Hacettepe University

Gebze Technical University
Anadolu University

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Nucleophilic substitution reactions of N₄P₄Cl ₈, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, ¹H and ³¹P NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.

Original language	English
Pages (from-to)	125-135
Number of pages	11
Journal	Journal of Chemical Sciences
Volume	121
Issue number	2
DOIs	https://doi.org/10.1007/s12039-009-0014-y
Publication status	Published - Mar 2009

Keywords

Amino phosphazenes
Cyclotetraphosphazenes
Spiro-phosphazene
X-ray

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10.1007/s12039-009-0014-y

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Ibişoǧlu, H., Çiftçi, G. Y., Kiliç, A., Tanriverdi, E., Ilker, Ü. N., Hakan, D., & Hökelek, T. (2009). Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene. Journal of Chemical Sciences, 121(2), 125-135. https://doi.org/10.1007/s12039-009-0014-y

@article{7d38c7f3b32b465f93cc3f9ffd18b270,

title = "Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene",

abstract = "Nucleophilic substitution reactions of N4P4Cl 8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, 1H and 31P NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.",

keywords = "Amino phosphazenes, Cyclotetraphosphazenes, Spiro-phosphazene, X-ray",

author = "Hanife Ibi{\c s}oǧlu and {\c C}ift{\c c}i, \{G{\"o}n{\"u}l Yenilmez\} and Adem Kili{\c c} and Esra Tanriverdi and Ilker, \{{\"U} N.\} and Dal Hakan and Tuncer H{\"o}kelek",

year = "2009",

month = mar,

doi = "10.1007/s12039-009-0014-y",

language = "English",

volume = "121",

pages = "125--135",

journal = "Journal of Chemical Sciences",

issn = "0974-3626",

publisher = "Springer India",

number = "2",

}

Ibişoǧlu, H, Çiftçi, GY, Kiliç, A, Tanriverdi, E, Ilker, ÜN, Hakan, D & Hökelek, T 2009, 'Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene', Journal of Chemical Sciences, vol. 121, no. 2, pp. 125-135. https://doi.org/10.1007/s12039-009-0014-y

Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene. / Ibişoǧlu, Hanife; Çiftçi, Gönül Yenilmez; Kiliç, Adem et al.
In: Journal of Chemical Sciences, Vol. 121, No. 2, 03.2009, p. 125-135.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

AU - Ibişoǧlu, Hanife

AU - Çiftçi, Gönül Yenilmez

AU - Kiliç, Adem

AU - Tanriverdi, Esra

AU - Ilker, Ü N.

AU - Hakan, Dal

AU - Hökelek, Tuncer

PY - 2009/3

Y1 - 2009/3

N2 - Nucleophilic substitution reactions of N4P4Cl 8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, 1H and 31P NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.

AB - Nucleophilic substitution reactions of N4P4Cl 8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, 1H and 31P NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.

KW - Amino phosphazenes

KW - Cyclotetraphosphazenes

KW - Spiro-phosphazene

KW - X-ray

UR - https://www.scopus.com/pages/publications/67649277714

U2 - 10.1007/s12039-009-0014-y

DO - 10.1007/s12039-009-0014-y

M3 - Article

AN - SCOPUS:67649277714

SN - 0974-3626

VL - 121

SP - 125

EP - 135

JO - Journal of Chemical Sciences

JF - Journal of Chemical Sciences

IS - 2

ER -

Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

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