Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate

Serkan Öncüoǧlu; Nefise Dilek; Nagihan Çaylak Delibaş; Yavuz Ergün; Tuncer Hökelek

doi:10.1107/S1600536814002098

Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate

Serkan Öncüoǧlu
, Nefise Dilek
, Nagihan Çaylak Delibaş
, Yavuz Ergün
, Tuncer Hökelek

Hacettepe University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, C₁₇H₁₇NO₂, the carbazole skeleton includes an ethoxycarbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking interactions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent molecules [centroid-centroid distances = 3.9473 (8) and 3.7758 (8) Å, respectively]. Weak C - H⋯π interactions are also present.

Original language	English
Pages (from-to)	o240
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	70
Issue number	3
DOIs	https://doi.org/10.1107/S1600536814002098
Publication status	Published - Mar 2014

Keywords

Data-to-parameter ratio = 15.1
Mean σ(C-C) = 0.002 Å
R factor = 0.049
Single-crystal X-ray study
T = 296 K
wR factor = 0.133

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title = "Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate",

abstract = "In the title compound, C17H17NO2, the carbazole skeleton includes an ethoxycarbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) {\AA}], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking interactions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent molecules [centroid-centroid distances = 3.9473 (8) and 3.7758 (8) {\AA}, respectively]. Weak C - H⋯π interactions are also present.",

keywords = "Data-to-parameter ratio = 15.1, Mean σ(C-C) = 0.002 {\AA}, R factor = 0.049, Single-crystal X-ray study, T = 296 K, wR factor = 0.133",

author = "Serkan {\"O}nc{\"u}oǧlu and Nefise Dilek and \{{\c C}aylak Deliba{\c s}\}, Nagihan and Yavuz Erg{\"u}n and Tuncer H{\"o}kelek",

year = "2014",

month = mar,

doi = "10.1107/S1600536814002098",

language = "English",

volume = "70",

pages = "o240",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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TY - JOUR

T1 - Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate

AU - Öncüoǧlu, Serkan

AU - Dilek, Nefise

AU - Çaylak Delibaş, Nagihan

AU - Ergün, Yavuz

AU - Hökelek, Tuncer

PY - 2014/3

Y1 - 2014/3

N2 - In the title compound, C17H17NO2, the carbazole skeleton includes an ethoxycarbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking interactions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent molecules [centroid-centroid distances = 3.9473 (8) and 3.7758 (8) Å, respectively]. Weak C - H⋯π interactions are also present.

AB - In the title compound, C17H17NO2, the carbazole skeleton includes an ethoxycarbonyl group at the 3-position. The indole three-ring system is almost planar [maximum deviation = 0.065 (2) Å], and the ethyl ester group is inclined to its mean plane by 15.48 (2)°. In the crystal, there are π-π stacking interactions between parallel benzene rings and between parallel benzene and pyrrole rings of adjacent molecules [centroid-centroid distances = 3.9473 (8) and 3.7758 (8) Å, respectively]. Weak C - H⋯π interactions are also present.

KW - Data-to-parameter ratio = 15.1

KW - Mean σ(C-C) = 0.002 Å

KW - R factor = 0.049

KW - Single-crystal X-ray study

KW - T = 296 K

KW - wR factor = 0.133

UR - https://www.scopus.com/pages/publications/84897691575

U2 - 10.1107/S1600536814002098

DO - 10.1107/S1600536814002098

M3 - Article

C2 - 24764961

AN - SCOPUS:84897691575

SN - 1600-5368

VL - 70

SP - o240

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Ethyl 4,9-dimethyl-9H-carbazole-3-carboxylate

Abstract

Keywords

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