Electrochemical synthesis of soluble sulfonated poly(3-methyl thiophene)

Yasemin Arslan Udum; Kadir Pekmez; Attila Yildiz

doi:10.1016/j.eurpolymj.2004.01.007

Electrochemical synthesis of soluble sulfonated poly(3-methyl thiophene)

Yasemin Arslan Udum
, Kadir Pekmez
, Attila Yildiz

Division of Analytical Chemistry (Faculty of Science, Science-Literature, Basic Sciences)

Hacettepe University

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Electrochemical polymerization of poly(3-methyl thiophene) films (3-MTy) which are self-doped with SO₃^- was investigated. The sulfonated poly(3-methyl thiophene) films synthesized from the solution which contained different amounts of HSO₃F. The sulfonated polymer films were found to be soluble in DMF and KOH. The solubility values increased and the conductivity values decreased with the increase in sulfonation ratio. The resulting polymers were characterized by cyclic voltammetry, UV-Vis, FT-IR, elemental analysis, dry conductivity measurements and SEM techniques.

Original language	English
Pages (from-to)	1057-1062
Number of pages	6
Journal	European Polymer Journal
Volume	40
Issue number	6
DOIs	https://doi.org/10.1016/j.eurpolymj.2004.01.007
Publication status	Published - Jun 2004

Keywords

Fluorosulfonic acid
In situ sulfonation
Poly(3-methyl thiophene)
Solubility
Sulfonated poly(3-methyl thiophene)

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10.1016/j.eurpolymj.2004.01.007

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title = "Electrochemical synthesis of soluble sulfonated poly(3-methyl thiophene)",

abstract = "Electrochemical polymerization of poly(3-methyl thiophene) films (3-MTy) which are self-doped with SO3- was investigated. The sulfonated poly(3-methyl thiophene) films synthesized from the solution which contained different amounts of HSO3F. The sulfonated polymer films were found to be soluble in DMF and KOH. The solubility values increased and the conductivity values decreased with the increase in sulfonation ratio. The resulting polymers were characterized by cyclic voltammetry, UV-Vis, FT-IR, elemental analysis, dry conductivity measurements and SEM techniques.",

keywords = "Fluorosulfonic acid, In situ sulfonation, Poly(3-methyl thiophene), Solubility, Sulfonated poly(3-methyl thiophene)",

author = "Udum, \{Yasemin Arslan\} and Kadir Pekmez and Attila Yildiz",

year = "2004",

month = jun,

doi = "10.1016/j.eurpolymj.2004.01.007",

language = "English",

volume = "40",

pages = "1057--1062",

journal = "European Polymer Journal",

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TY - JOUR

T1 - Electrochemical synthesis of soluble sulfonated poly(3-methyl thiophene)

AU - Udum, Yasemin Arslan

AU - Pekmez, Kadir

AU - Yildiz, Attila

PY - 2004/6

Y1 - 2004/6

N2 - Electrochemical polymerization of poly(3-methyl thiophene) films (3-MTy) which are self-doped with SO3- was investigated. The sulfonated poly(3-methyl thiophene) films synthesized from the solution which contained different amounts of HSO3F. The sulfonated polymer films were found to be soluble in DMF and KOH. The solubility values increased and the conductivity values decreased with the increase in sulfonation ratio. The resulting polymers were characterized by cyclic voltammetry, UV-Vis, FT-IR, elemental analysis, dry conductivity measurements and SEM techniques.

AB - Electrochemical polymerization of poly(3-methyl thiophene) films (3-MTy) which are self-doped with SO3- was investigated. The sulfonated poly(3-methyl thiophene) films synthesized from the solution which contained different amounts of HSO3F. The sulfonated polymer films were found to be soluble in DMF and KOH. The solubility values increased and the conductivity values decreased with the increase in sulfonation ratio. The resulting polymers were characterized by cyclic voltammetry, UV-Vis, FT-IR, elemental analysis, dry conductivity measurements and SEM techniques.

KW - Fluorosulfonic acid

KW - In situ sulfonation

KW - Poly(3-methyl thiophene)

KW - Solubility

KW - Sulfonated poly(3-methyl thiophene)

UR - https://www.scopus.com/pages/publications/2342629222

U2 - 10.1016/j.eurpolymj.2004.01.007

DO - 10.1016/j.eurpolymj.2004.01.007

M3 - Article

AN - SCOPUS:2342629222

SN - 0014-3057

VL - 40

SP - 1057

EP - 1062

JO - European Polymer Journal

JF - European Polymer Journal

IS - 6

ER -

Electrochemical synthesis of soluble sulfonated poly(3-methyl thiophene)

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Keywords

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