Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

Nurettin Baleioglu; Fatma Sevin; Ozden Ozel Evin; N. Bekir Peynircioglu

doi:10.1002/bbpc.19920960206

Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

Nurettin Baleioglu
, Fatma Sevin
, Ozden Ozel Evin
, N. Bekir Peynircioglu

Division of Organic Chemistry (Science, Faculty of Science and Literature, Faculty of Basic Sciences)

Hacettepe University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

Original language	English
Pages (from-to)	139-142
Number of pages	4
Journal	Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
Volume	96
Issue number	2
DOIs	https://doi.org/10.1002/bbpc.19920960206
Publication status	Published - 1992

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title = "Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers",

abstract = "Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.",

author = "Nurettin Baleioglu and Fatma Sevin and Evin, \{Ozden Ozel\} and Peynircioglu, \{N. Bekir\}",

year = "1992",

doi = "10.1002/bbpc.19920960206",

language = "English",

volume = "96",

pages = "139--142",

journal = "Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics",

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T1 - Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

AU - Baleioglu, Nurettin

AU - Sevin, Fatma

AU - Evin, Ozden Ozel

AU - Peynircioglu, N. Bekir

PY - 1992

Y1 - 1992

N2 - Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

AB - Relative kinetic acidity measurements have shown that the cyclobutyl group has the ability to stabilize an adjacent carbanion center similar to vinyl and cyclopropyl groups, although to a lesser extent. The results of semiempirical calculations (MNDO) covering all the mentioned substituents, including the isopropyl group correlate well with the experimentally determined relative kinetic acidities.

UR - https://www.scopus.com/pages/publications/0026813517

U2 - 10.1002/bbpc.19920960206

DO - 10.1002/bbpc.19920960206

M3 - Article

AN - SCOPUS:0026813517

SN - 0005-9021

VL - 96

SP - 139

EP - 142

JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics

IS - 2

ER -

Effect of alkyl groups on carbanion stability Part I. Interaction of small rings with adjacent carbanion centers

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