Diaquabis(N,N-diethylnicotinamide-N1) bis(2-hydroxybenzoa to-O)cobalt(II)

Tuncer Hokelek; Hacali Necefoglu

doi:10.1107/S0108270196013170

Diaquabis(N,N-diethylnicotinamide-N¹) bis(2-hydroxybenzoa to-O)cobalt(II)

Tuncer Hokelek
, Hacali Necefoglu

Hacettepe University

Hacettepe University

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The title monomeric centrosymmetric cobalt complex, [Co(C₇H₅O₃)₂ (C₁₀H₁₄N₂O)₂( H₂O) ₂], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All ligands are coordinated to the Co atom as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) angstroms. The water molecules are hydrogen bonded to the carboxyl O atoms [O···O 2.687 (5) angstroms].

Original language	English
Pages (from-to)	187-189
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	53
Issue number	pt 2
DOIs	https://doi.org/10.1107/S0108270196013170
Publication status	Published - 1 Jan 1997

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title = "Diaquabis(N,N-diethylnicotinamide-N1) bis(2-hydroxybenzoa to-O)cobalt(II)",

abstract = "The title monomeric centrosymmetric cobalt complex, [Co(C7H5O3)2 (C10H14N2O)2( H2O) 2], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All ligands are coordinated to the Co atom as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) angstroms. The water molecules are hydrogen bonded to the carboxyl O atoms [O···O 2.687 (5) angstroms].",

author = "Tuncer Hokelek and Hacali Necefoglu",

year = "1997",

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doi = "10.1107/S0108270196013170",

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T1 - Diaquabis(N,N-diethylnicotinamide-N1) bis(2-hydroxybenzoa to-O)cobalt(II)

AU - Hokelek, Tuncer

AU - Necefoglu, Hacali

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The title monomeric centrosymmetric cobalt complex, [Co(C7H5O3)2 (C10H14N2O)2( H2O) 2], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All ligands are coordinated to the Co atom as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) angstroms. The water molecules are hydrogen bonded to the carboxyl O atoms [O···O 2.687 (5) angstroms].

AB - The title monomeric centrosymmetric cobalt complex, [Co(C7H5O3)2 (C10H14N2O)2( H2O) 2], contains two water molecules, two 4-hydroxybenzoate ligands and two diethylnicotinamide (DENA) ligands. All ligands are coordinated to the Co atom as monodentate ligands. The four nearest O atoms around the Co atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination completed by the pyridine N atoms of the DENA ligand at a distance of 2.141 (5) angstroms. The water molecules are hydrogen bonded to the carboxyl O atoms [O···O 2.687 (5) angstroms].

UR - https://www.scopus.com/pages/publications/0031078475

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M3 - Article

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - pt 2

ER -

Diaquabis(N,N-diethylnicotinamide-N¹) bis(2-hydroxybenzoa to-O)cobalt(II)

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