Diaquabis(2-bromo-benzoato-κO)bis-(N,N-diethyl-nicotinamide-κN 1)zinc(II)

  • Tuncer Hökelek
  • , Hakan Dal
  • , Bariş Tercan
  • , F. Elif Özbek
  • , Hacali Necefoǧlu

Research output: Contribution to journalArticlepeer-review

10 Citations (Scopus)

Abstract

In the centrosymmetric title complex, [Zn(C7H4BrO2)2(C10H14N2O)2(H2O)2], the ZnII atom is located on an inversion center. The asymmetric unit contains one 2-bromo-benzoate (BB), one diethyl-nicotinamide (DENA) ligand and one coordinating water molecule. The four O atoms in the equatorial plane around the Zn atom form a slightly distorted square-planar arrangement, while the slightly distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. The dihedral angle between the carboxyl group and the adjacent benzene ring is 85.51 (12)°, while the pyridine and benzene rings are oriented at a dihedral angle of 44.07 (6)°. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains.

Original languageEnglish
Pages (from-to)m481-m482
JournalActa Crystallographica Section E: Structure Reports Online
Volume65
Issue number5
DOIs
Publication statusPublished - 2009

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