Diaqua-bis(N,N-diethyl-nicotinamide-N 1)bis-(4-formyl-benzoato- O)cobalt(II)

Mustafa Sertçelik; Bar Tercan; Ertan Ahin; Hacali Necefolu; Tuncer Hökelek

doi:10.1107/S1600536809008265

Diaqua-bis(N,N-diethyl-nicotinamide-N ¹)bis-(4-formyl-benzoato- O)cobalt(II)

Mustafa Sertçelik
, Bar Tercan
, Ertan Ahin
, Hacali Necefolu
, Tuncer Hökelek

Hacettepe University

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

In the crystal structure of the title Co^II complex, [Co(C ₈H₅O₃)₂(C₁₀H ₁₄N_2O)₂(H₂O)₂], the metal centre is located on an inversion center and is coordinated by two 4-formyl-benzoate (FOB), two diethyl-nicotinamide (DENA) ligands and two water mol-ecules in a slightly distorted CoO4N2 octa-hedral geometry. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains. π-π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid-centroid distance = 3.652 (3) Å] further stabilize the crystal structure.

Original language	English
Pages (from-to)	m389-m390
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	4
DOIs	https://doi.org/10.1107/S1600536809008265
Publication status	Published - 2009

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title = "Diaqua-bis(N,N-diethyl-nicotinamide-N 1)bis-(4-formyl-benzoato- O)cobalt(II)",

abstract = "In the crystal structure of the title CoII complex, [Co(C 8H5O3)2(C10H 14N2O)2(H2O)2], the metal centre is located on an inversion center and is coordinated by two 4-formyl-benzoate (FOB), two diethyl-nicotinamide (DENA) ligands and two water mol-ecules in a slightly distorted CoO4N2 octa-hedral geometry. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains. π-π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid-centroid distance = 3.652 (3) {\AA}] further stabilize the crystal structure.",

author = "Mustafa Sert{\c c}elik and Bar Tercan and Ertan Ahin and Hacali Necefolu and Tuncer H{\"o}kelek",

year = "2009",

doi = "10.1107/S1600536809008265",

language = "English",

volume = "65",

pages = "m389--m390",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - Diaqua-bis(N,N-diethyl-nicotinamide-N 1)bis-(4-formyl-benzoato- O)cobalt(II)

AU - Sertçelik, Mustafa

AU - Tercan, Bar

AU - Ahin, Ertan

AU - Necefolu, Hacali

AU - Hökelek, Tuncer

PY - 2009

Y1 - 2009

N2 - In the crystal structure of the title CoII complex, [Co(C 8H5O3)2(C10H 14N2O)2(H2O)2], the metal centre is located on an inversion center and is coordinated by two 4-formyl-benzoate (FOB), two diethyl-nicotinamide (DENA) ligands and two water mol-ecules in a slightly distorted CoO4N2 octa-hedral geometry. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains. π-π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid-centroid distance = 3.652 (3) Å] further stabilize the crystal structure.

AB - In the crystal structure of the title CoII complex, [Co(C 8H5O3)2(C10H 14N2O)2(H2O)2], the metal centre is located on an inversion center and is coordinated by two 4-formyl-benzoate (FOB), two diethyl-nicotinamide (DENA) ligands and two water mol-ecules in a slightly distorted CoO4N2 octa-hedral geometry. In the crystal structure, O - H⋯O hydrogen bonds link the mol-ecules into infinite chains. π-π contacts between the parallel pyridine rings of neighboring DENA ligands [centroid-centroid distance = 3.652 (3) Å] further stabilize the crystal structure.

UR - https://www.scopus.com/pages/publications/64149093750

U2 - 10.1107/S1600536809008265

DO - 10.1107/S1600536809008265

M3 - Article

C2 - 21582339

AN - SCOPUS:64149093750

SN - 1600-5368

VL - 65

SP - m389-m390

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Diaqua-bis(N,N-diethyl-nicotinamide-N ¹)bis-(4-formyl-benzoato- O)cobalt(II)

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