Crystal structure of 4-({5-[(E)-(3,5-difluorophenyl)-diazenyl]-2-hydroxybenzylidene}amino)-2,2,6,6-tetramethylpiperidin-1-oxyl

The asymmetric unit of the title compound, C₂₂H₂₅F₂N₄O₂, contains two crystallographically independent molecules. In one molecule, the two benzene rings are oriented at a dihedral angle of 1.93 (10)° and in the other molecule the corresponding dihedral angle is 7.19 (9)°. The piperidine rings in the two molecules adopt a similar distorted chair conformation, and both have pseudomirror planes passing through the N-O bonds. An intramolecular O-H⋯N hydrogen bond between the hydroxy group and the imine N atom is observed in both molecules. In the crystal, weak C-H⋯O and C-H⋯F hydrogen bonds, enclosing R²₂(6) ring motifs, and weak π-π stacking interactions link the molecules into a three-dimensional supramolecular network, with centroid-tocentroid distances between the nearly parallel phenyl and benzene rings of adjacent molecules of 3.975 (2) and 3.782 (2) Å.