Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN1)zinc(II)

Hacali Necefoǧlu; Füreya Elif Özbek; Vedat Aktaş; Bariş Tercan; Tuncer Hökelek

doi:10.1107/S1600536811006830

Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN¹)zinc(II)

Hacali Necefoǧlu
, Füreya Elif Özbek
, Vedat Aktaş
, Bariş Tercan
, Tuncer Hökelek

Hacettepe University

Kafkas University
Karabuk University

Research output: Contribution to journal › Article › peer-review

Abstract

The title Zn^II complex, [Zn(C₉H₉O ₂)₂(C₆H₆N₂O) ₂], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn^II ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, intermolecular N - H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. C - H⋯O interactions also occur as well as two weak C - H⋯π interactions involving the benzene rings.

Original language	English
Pages (from-to)	m382-m383
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	3
DOIs	https://doi.org/10.1107/S1600536811006830
Publication status	Published - Mar 2011

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title = "Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN1)zinc(II)",

abstract = "The title ZnII complex, [Zn(C9H9O 2)2(C6H6N2O) 2], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the ZnII ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, intermolecular N - H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. C - H⋯O interactions also occur as well as two weak C - H⋯π interactions involving the benzene rings.",

author = "Hacali Necefoǧlu and {\"O}zbek, \{F{\"u}reya Elif\} and Vedat Akta{\c s} and Bari{\c s} Tercan and Tuncer H{\"o}kelek",

year = "2011",

month = mar,

doi = "10.1107/S1600536811006830",

language = "English",

volume = "67",

pages = "m382--m383",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "3",

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TY - JOUR

T1 - Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN1)zinc(II)

AU - Necefoǧlu, Hacali

AU - Özbek, Füreya Elif

AU - Aktaş, Vedat

AU - Tercan, Bariş

AU - Hökelek, Tuncer

PY - 2011/3

Y1 - 2011/3

N2 - The title ZnII complex, [Zn(C9H9O 2)2(C6H6N2O) 2], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the ZnII ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, intermolecular N - H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. C - H⋯O interactions also occur as well as two weak C - H⋯π interactions involving the benzene rings.

AB - The title ZnII complex, [Zn(C9H9O 2)2(C6H6N2O) 2], contains two 4-ethylbenzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the ZnII ion. The dihedral angles between the carboxylate groups and the adjacent benzene rings are 10.33 (13) and 2.38 (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46 (5) and 81.09 (6)°. In the crystal, intermolecular N - H⋯O hydrogen bonds link the molecules, forming a three-dimensional network. C - H⋯O interactions also occur as well as two weak C - H⋯π interactions involving the benzene rings.

UR - https://www.scopus.com/pages/publications/79952435640

U2 - 10.1107/S1600536811006830

DO - 10.1107/S1600536811006830

M3 - Article

AN - SCOPUS:79952435640

SN - 1600-5368

VL - 67

SP - m382-m383

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 3

ER -

Bis(4-ethylbenzoato-κO)bis(nicotinamide-κN¹)zinc(II)

Abstract

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