Bis(μ-4-methylbenzoato)-κ3 O,O′: O;κ3 O:O,O′-bis[aqua(4-methylbenzoato-κ2 O,O′)(nicotinamide-κN 1)cadmium]

  • Öznur Dincel
  • , Bariş Tercan
  • , Efdal Çimen
  • , Hacali Necefoǧlu
  • , Tuncer Hökelek

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

In the dinuclear centrosymmetric title compound, [Cd2(C8H7O2)4(C6H6N2O) 2(H2O)2], the CdII ion is chelated by two carboxylate groups from 4-methylbenzoate anions, and is further coordinated by one nicotinamide and one water molecule; a carboxylate O atom from an adjacent 4-methylbenzoate anion bridges to the CdII ion, completing the irregular coordination sphere of the seven ligand atoms. In the crystal, intermolecular O-H⋯O, N-H⋯O and weak C-H⋯O hydrogen bonds link the molecules into a three-dimensional network. The methylbenzene moiety of one bridging 4-methylbenzoate anion is disordered over two orientations of equal occupancy.

Original languageEnglish
Pages (from-to)m1510-m1511
JournalActa Crystallographica Section E: Structure Reports Online
Volume68
Issue number12
DOIs
Publication statusPublished - Dec 2012

Keywords

  • R factor = 0.019
  • T = 100 K
  • data-to-parameter ratio = 16.3
  • disorder in main residue
  • mean ω(C-C) = 0.003 Å
  • single-crystal X-ray study
  • wR factor = 0.048

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