Bis(μ-3-hydroxybenzoato)-κ 3 O 1,O 1′:O 1;κ 3 O 1:O 1,O 1′-bis-[(3-hydroxybenzoato-κ 2 O,O′)(iso-nicotinamide-κN 1)cadmium] tetra-hydrate

Ibrahim Göker Zaman; Nagihan Çaylak Delibaş; Hacali Necefoǧlu; Tuncer Hökelek

doi:10.1107/S160053681200219X

Bis(μ-3-hydroxybenzoato)-κ ³ O ¹,O ^1′:O ¹;κ ³ O ¹:O ¹,O ^1′-bis-[(3-hydroxybenzoato-κ ² O,O′)(iso-nicotinamide-κN ¹)cadmium] tetra-hydrate

Ibrahim Göker Zaman
, Nagihan Çaylak Delibaş
, Hacali Necefoǧlu
, Tuncer Hökelek

Hacettepe University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

In the title centrosymmetric binuclear Cd ^II compound, [Cd ₂(C ₇H ₅O ₃) ₄(C ₆H ₆N ₂O) ₂]·4H ₂O, the six-coordinated Cd ^II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure.

Original language	English
Pages (from-to)	m198-m199
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	68
Issue number	2
DOIs	https://doi.org/10.1107/S160053681200219X
Publication status	Published - Feb 2012

Keywords

R factor = 0.017
T = 100 K
data-to-parameter ratio = 12.6
mean σ(C-C) = 0.002 Å
single-crystal X-ray study
wR factor = 0.043

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10.1107/S160053681200219X

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@article{f90e92ac4e164eb9a62ca37d8d2eaef5,

title = "Bis(μ-3-hydroxybenzoato)-κ 3 O 1,O 1′:O 1;κ 3 O 1:O 1,O 1′-bis-[(3-hydroxybenzoato-κ 2 O,O′)(iso-nicotinamide-κN 1)cadmium] tetra-hydrate",

abstract = "In the title centrosymmetric binuclear Cd II compound, [Cd 2(C 7H 5O 3) 4(C 6H 6N 2O) 2]·4H 2O, the six-coordinated Cd II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) {\AA}] may further stabilize the structure.",

keywords = "R factor = 0.017, T = 100 K, data-to-parameter ratio = 12.6, mean σ(C-C) = 0.002 {\AA}, single-crystal X-ray study, wR factor = 0.043",

author = "Zaman, \{Ibrahim G{\"o}ker\} and \{{\c C}aylak Deliba{\c s}\}, Nagihan and Hacali Necefoǧlu and Tuncer H{\"o}kelek",

year = "2012",

month = feb,

doi = "10.1107/S160053681200219X",

language = "English",

volume = "68",

pages = "m198--m199",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

Bis(μ-3-hydroxybenzoato)-κ ³ O ¹,O ^1′:O ¹;κ ³ O ¹:O ¹,O ^1′-bis-[(3-hydroxybenzoato-κ ² O,O′)(iso-nicotinamide-κN ¹)cadmium] tetra-hydrate. / Zaman, Ibrahim Göker; Çaylak Delibaş, Nagihan; Necefoǧlu, Hacali et al.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 68, No. 2, 02.2012, p. m198-m199.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Bis(μ-3-hydroxybenzoato)-κ 3 O 1,O 1′:O 1;κ 3 O 1:O 1,O 1′-bis-[(3-hydroxybenzoato-κ 2 O,O′)(iso-nicotinamide-κN 1)cadmium] tetra-hydrate

AU - Zaman, Ibrahim Göker

AU - Çaylak Delibaş, Nagihan

AU - Necefoǧlu, Hacali

AU - Hökelek, Tuncer

PY - 2012/2

Y1 - 2012/2

N2 - In the title centrosymmetric binuclear Cd II compound, [Cd 2(C 7H 5O 3) 4(C 6H 6N 2O) 2]·4H 2O, the six-coordinated Cd II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure.

AB - In the title centrosymmetric binuclear Cd II compound, [Cd 2(C 7H 5O 3) 4(C 6H 6N 2O) 2]·4H 2O, the six-coordinated Cd II atom is chelated by the carboxyl-ate groups of the two 3-hy-droxy-benzoate (HB) anions; the two monomeric units are bridged through the two O atoms of the two carboxylate groups. In the crystal, O - H⋯O, N - H⋯O and C - H⋯O hydrogen bonds link the molecules into a three-dimensional network. π-π Contacts between the pyridine rings and between the benzene rings [centroid-centroid distances = 3.770 (1), 3.769 (1) and 3.632 (1) Å] may further stabilize the structure.

KW - R factor = 0.017

KW - T = 100 K

KW - data-to-parameter ratio = 12.6

KW - mean σ(C-C) = 0.002 Å

KW - single-crystal X-ray study

KW - wR factor = 0.043

UR - https://www.scopus.com/pages/publications/84856971757

U2 - 10.1107/S160053681200219X

DO - 10.1107/S160053681200219X

M3 - Article

AN - SCOPUS:84856971757

SN - 1600-5368

VL - 68

SP - m198-m199

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Bis(μ-3-hydroxybenzoato)-κ ³ O ¹,O ^1′:O ¹;κ ³ O ¹:O ¹,O ^1′-bis-[(3-hydroxybenzoato-κ ² O,O′)(iso-nicotinamide-κN ¹)cadmium] tetra-hydrate

Abstract

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