(Benzoylacetonato)chloro(l ,10-phenanthroline)copper(II)

Yalçm Elerman; Hülya Kara; Sabahat Özcan; Engin Kendi

doi:10.1107/S0108270100007411

(Benzoylacetonato)chloro(l ,10-phenanthroline)copper(II)

Yalçm Elerman
, Hülya Kara
, Sabahat Özcan
, Engin Kendi

Hacettepe University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The crystal structure of the title compound, chloro(l,10phenanthroline-N,N′)(l-phenyl-l,3-butanedionato-O,O′) copper(II), [CuCl(C₁₀H₉O₂)(C₁₂H ₈N₂)], has been determined. The Cu^II ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)1 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Å, respectively.

Original language	English
Pages (from-to)	950-951
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	8
DOIs	https://doi.org/10.1107/S0108270100007411
Publication status	Published - 2000

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title = "(Benzoylacetonato)chloro(l ,10-phenanthroline)copper(II)",

abstract = "The crystal structure of the title compound, chloro(l,10phenanthroline-N,N′)(l-phenyl-l,3-butanedionato-O,O′) copper(II), [CuCl(C10H9O2)(C12H 8N2)], has been determined. The CuII ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)1 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) {\AA}, respectively.",

author = "Yal{\c c}m Elerman and H{\"u}lya Kara and Sabahat {\"O}zcan and Engin Kendi",

year = "2000",

doi = "10.1107/S0108270100007411",

language = "English",

volume = "56",

pages = "950--951",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "8",

}

TY - JOUR

T1 - (Benzoylacetonato)chloro(l ,10-phenanthroline)copper(II)

AU - Elerman, Yalçm

AU - Kara, Hülya

AU - Özcan, Sabahat

AU - Kendi, Engin

PY - 2000

Y1 - 2000

N2 - The crystal structure of the title compound, chloro(l,10phenanthroline-N,N′)(l-phenyl-l,3-butanedionato-O,O′) copper(II), [CuCl(C10H9O2)(C12H 8N2)], has been determined. The CuII ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)1 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Å, respectively.

AB - The crystal structure of the title compound, chloro(l,10phenanthroline-N,N′)(l-phenyl-l,3-butanedionato-O,O′) copper(II), [CuCl(C10H9O2)(C12H 8N2)], has been determined. The CuII ion displays a distorted square-pyramidal coordination, being linked to the two O atoms of the benzoylacetonate ligand and the two N atoms of the 1,10-phenanthroline ligand in the basal plane, and the Cl atom in the apical site. The Cu-N, Cu-O and Cu-Cl bond lengths are 2.043 (2)1 2.025 (2), 1.914 (2)/1.941 (2) and 2.485 (1) Å, respectively.

UR - https://www.scopus.com/pages/publications/0034239233

U2 - 10.1107/S0108270100007411

DO - 10.1107/S0108270100007411

M3 - Article

AN - SCOPUS:0034239233

SN - 0108-2701

VL - 56

SP - 950

EP - 951

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 8

ER -

(Benzoylacetonato)chloro(l ,10-phenanthroline)copper(II)

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