An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

D. Gürçay; Z. Kantarci; S. Aydin

doi:10.1016/S0022-2860(98)00838-2

An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

D. Gürçay
, Z. Kantarci
, S. Aydin

Gazi University

Research output: Contribution to journal › Article › peer-review

Abstract

Evidence based on the IR and Raman spectral features of Hg(CN)₂ in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

Original language	English
Pages (from-to)	65-68
Number of pages	4
Journal	Journal of Molecular Structure
Volume	482-483
DOIs	https://doi.org/10.1016/S0022-2860(98)00838-2
Publication status	Published - 25 May 1999
Externally published	Yes

Keywords

Infrared spectra
Mercuric cyanide
Raman spectra
Solute-solvent interactions
Solution chemistry

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10.1016/S0022-2860(98)00838-2

Cite this

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title = "An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents",

abstract = "Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.",

keywords = "Infrared spectra, Mercuric cyanide, Raman spectra, Solute-solvent interactions, Solution chemistry",

author = "D. G{\"u}r{\c c}ay and Z. Kantarci and S. Aydin",

year = "1999",

month = may,

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doi = "10.1016/S0022-2860(98)00838-2",

language = "English",

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pages = "65--68",

journal = "Journal of Molecular Structure",

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T1 - An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

AU - Gürçay, D.

AU - Kantarci, Z.

AU - Aydin, S.

PY - 1999/5/25

Y1 - 1999/5/25

N2 - Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

AB - Evidence based on the IR and Raman spectral features of Hg(CN)2 in twelve solvents with widely different donor strengths supports the view that increasing solvent coordination to the Hg atom leads to a progressive reduction of the C-Hg-C angle from 180°. For solvents of high donor strength (e.g. piperidine) the C-Hg-C interbond angle may approach 145°.

KW - Infrared spectra

KW - Mercuric cyanide

KW - Raman spectra

KW - Solute-solvent interactions

KW - Solution chemistry

UR - https://www.scopus.com/pages/publications/0345465615

U2 - 10.1016/S0022-2860(98)00838-2

DO - 10.1016/S0022-2860(98)00838-2

M3 - Article

AN - SCOPUS:0345465615

SN - 0022-2860

VL - 482-483

SP - 65

EP - 68

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

ER -

An infrared and Raman spectroscopic study on the solvation of mercury(II) cyanide in aprotic donor solvents

Abstract

Keywords

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