An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C10H8N2)Cd(CN)4 · 2C6H6 and Cd(C10H8N2)Hg(CN)4 · 2C6H6

Sevgi Bayari; Ziya Kantarci; Sevim Akyüz

doi:10.1007/BF00708788

An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C₁₀H₈N₂)Cd(CN)₄ · 2C₆H₆ and Cd(C₁₀H₈N₂)Hg(CN)₄ · 2C₆H₆

Sevgi Bayari
, Ziya Kantarci
, Sevim Akyüz

Gazi University
Fen Fakültesi

Research output: Contribution to journal › Review article › peer-review

32 Citations (Scopus)

Abstract

Two new benzene clathrates of the form Cd(4,4′-bipyridyl)M(CN)₄ · 2C₆H₆, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.

Original language	English
Pages (from-to)	291-302
Number of pages	12
Journal	Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
Volume	17
Issue number	3
DOIs	https://doi.org/10.1007/BF00708788
Publication status	Published - Sept 1994
Externally published	Yes

Keywords

4,4′-bipyridyl benzene inclusion compounds
Cd-bipyridyl tetracyanometallate complexes
Hofmann-Td-type clathrate
IR and Raman spectra

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10.1007/BF00708788

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@article{14114e78f34349fbb3697b8e0524871f,

title = "An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C10H8N2)Cd(CN)4 · 2C6H6 and Cd(C10H8N2)Hg(CN)4 · 2C6H6",

abstract = "Two new benzene clathrates of the form Cd(4,4′-bipyridyl)M(CN)4 · 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.",

keywords = "4,4′-bipyridyl benzene inclusion compounds, Cd-bipyridyl tetracyanometallate complexes, Hofmann-Td-type clathrate, IR and Raman spectra",

author = "Sevgi Bayari and Ziya Kantarci and Sevim Aky{\"u}z",

year = "1994",

month = sep,

doi = "10.1007/BF00708788",

language = "English",

volume = "17",

pages = "291--302",

journal = "Journal of Inclusion Phenomena and Molecular Recognition in Chemistry",

issn = "0923-0750",

publisher = "Editura Stiintifica F. M. R.",

number = "3",

}

Bayari, S, Kantarci, Z & Akyüz, S 1994, 'An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C₁₀H₈N₂)Cd(CN)₄ · 2C₆H₆ and Cd(C₁₀H₈N₂)Hg(CN)₄ · 2C₆H₆', Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, vol. 17, no. 3, pp. 291-302. https://doi.org/10.1007/BF00708788

An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C₁₀H₈N₂)Cd(CN)₄ · 2C₆H₆ and Cd(C₁₀H₈N₂)Hg(CN)₄ · 2C₆H₆. / Bayari, Sevgi; Kantarci, Ziya; Akyüz, Sevim.
In: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 17, No. 3, 09.1994, p. 291-302.

Research output: Contribution to journal › Review article › peer-review

TY - JOUR

T1 - An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates

T2 - Cd(C10H8N2)Cd(CN)4 · 2C6H6 and Cd(C10H8N2)Hg(CN)4 · 2C6H6

AU - Bayari, Sevgi

AU - Kantarci, Ziya

AU - Akyüz, Sevim

PY - 1994/9

Y1 - 1994/9

N2 - Two new benzene clathrates of the form Cd(4,4′-bipyridyl)M(CN)4 · 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.

AB - Two new benzene clathrates of the form Cd(4,4′-bipyridyl)M(CN)4 · 2C6H6, (M=Cd or Hg) have been prepared in powder form. Their spectral data were compared with those of the corresponding host complexes and found to be consistent with the host structure found in Td-type clathrates.

KW - 4,4′-bipyridyl benzene inclusion compounds

KW - Cd-bipyridyl tetracyanometallate complexes

KW - Hofmann-Td-type clathrate

KW - IR and Raman spectra

UR - https://www.scopus.com/pages/publications/0011613815

U2 - 10.1007/BF00708788

DO - 10.1007/BF00708788

M3 - Review article

AN - SCOPUS:0011613815

SN - 0923-0750

VL - 17

SP - 291

EP - 302

JO - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

JF - Journal of Inclusion Phenomena and Molecular Recognition in Chemistry

IS - 3

ER -

An infrared and Raman spectroscopic study of Td-type 4,4′-bipyridylcadmium(II) tetracyanometallate (II) benzene (1/2) clathrates: Cd(C₁₀H₈N₂)Cd(CN)₄ · 2C₆H₆ and Cd(C₁₀H₈N₂)Hg(CN)₄ · 2C₆H₆

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