Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles

Anastassiya A. Mashentseva; Nurzhigit Seitzhapar; Murat Barsbay; Nurgulim A. Aimanova; Assel N. Alimkhanova; Dmitriy A. Zheltov; Alisher M. Zhumabayev; Bakhtiyar S. Temirgaziev; Alimzhan A. Almanov; Daniyar T. Sadyrbekov

doi:10.1039/d3ra05347d

Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles

Anastassiya A. Mashentseva
, Nurzhigit Seitzhapar
, Murat Barsbay
, Nurgulim A. Aimanova
, Assel N. Alimkhanova
, Dmitriy A. Zheltov
, Alisher M. Zhumabayev
, Bakhtiyar S. Temirgaziev
, Alimzhan A. Almanov
, Daniyar T. Sadyrbekov

Division of Polymer Chemistry

Institute of Nuclear Physics, National Nuclear Center of the Republic of Kazakhstan
L.N. Gumilyov Eurasian National University
Buketov Karaganda State University

Research output: Contribution to journal › Article › peer-review

26 Citations (Scopus)

Abstract

This study investigates the sorption removal of lead(ii) ions using zinc oxide (ZnO) and copper(ii) oxide (CuO) nanoparticles synthesized through a wet burning method with the aid of plant extract from Serratula coronata L. The effect of plant collection time on polyphenol content was investigated and optimal conditions were determined. The structural and chemical properties of the nanoparticles were studied by scanning electron microscopy, energy dispersive analysis, X-ray phase analysis, and X-ray photoelectron spectroscopy. A comparative analysis of lead ion sorption on the surface of synthesized nanoparticles was conducted. The kinetic study revealed that the sorption process follows a pseudo-second-order mechanism, and the Freundlich sorption model provides a better fit for the experimental data. ZnO and CuO nanoparticles exhibited significant sorption capacities, with values of 163.6 and 153.8 mg g⁻¹, respectively.

Original language	English
Pages (from-to)	26839-26850
Number of pages	12
Journal	RSC Advances
Volume	13
Issue number	38
DOIs	https://doi.org/10.1039/d3ra05347d
Publication status	Published - 7 Sept 2023

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Mashentseva, A. A., Seitzhapar, N., Barsbay, M., Aimanova, N. A., Alimkhanova, A. N., Zheltov, D. A., Zhumabayev, A. M., Temirgaziev, B. S., Almanov, A. A., & Sadyrbekov, D. T. (2023). Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles. RSC Advances, 13(38), 26839-26850. https://doi.org/10.1039/d3ra05347d

@article{73d763314ec346648e46645bd429fff8,

title = "Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles",

abstract = "This study investigates the sorption removal of lead(ii) ions using zinc oxide (ZnO) and copper(ii) oxide (CuO) nanoparticles synthesized through a wet burning method with the aid of plant extract from Serratula coronata L. The effect of plant collection time on polyphenol content was investigated and optimal conditions were determined. The structural and chemical properties of the nanoparticles were studied by scanning electron microscopy, energy dispersive analysis, X-ray phase analysis, and X-ray photoelectron spectroscopy. A comparative analysis of lead ion sorption on the surface of synthesized nanoparticles was conducted. The kinetic study revealed that the sorption process follows a pseudo-second-order mechanism, and the Freundlich sorption model provides a better fit for the experimental data. ZnO and CuO nanoparticles exhibited significant sorption capacities, with values of 163.6 and 153.8 mg g−1, respectively.",

author = "Mashentseva, \{Anastassiya A.\} and Nurzhigit Seitzhapar and Murat Barsbay and Aimanova, \{Nurgulim A.\} and Alimkhanova, \{Assel N.\} and Zheltov, \{Dmitriy A.\} and Zhumabayev, \{Alisher M.\} and Temirgaziev, \{Bakhtiyar S.\} and Almanov, \{Alimzhan A.\} and Sadyrbekov, \{Daniyar T.\}",

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T1 - Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles

AU - Mashentseva, Anastassiya A.

AU - Seitzhapar, Nurzhigit

AU - Barsbay, Murat

AU - Aimanova, Nurgulim A.

AU - Alimkhanova, Assel N.

AU - Zheltov, Dmitriy A.

AU - Zhumabayev, Alisher M.

AU - Temirgaziev, Bakhtiyar S.

AU - Almanov, Alimzhan A.

AU - Sadyrbekov, Daniyar T.

PY - 2023/9/7

Y1 - 2023/9/7

N2 - This study investigates the sorption removal of lead(ii) ions using zinc oxide (ZnO) and copper(ii) oxide (CuO) nanoparticles synthesized through a wet burning method with the aid of plant extract from Serratula coronata L. The effect of plant collection time on polyphenol content was investigated and optimal conditions were determined. The structural and chemical properties of the nanoparticles were studied by scanning electron microscopy, energy dispersive analysis, X-ray phase analysis, and X-ray photoelectron spectroscopy. A comparative analysis of lead ion sorption on the surface of synthesized nanoparticles was conducted. The kinetic study revealed that the sorption process follows a pseudo-second-order mechanism, and the Freundlich sorption model provides a better fit for the experimental data. ZnO and CuO nanoparticles exhibited significant sorption capacities, with values of 163.6 and 153.8 mg g−1, respectively.

AB - This study investigates the sorption removal of lead(ii) ions using zinc oxide (ZnO) and copper(ii) oxide (CuO) nanoparticles synthesized through a wet burning method with the aid of plant extract from Serratula coronata L. The effect of plant collection time on polyphenol content was investigated and optimal conditions were determined. The structural and chemical properties of the nanoparticles were studied by scanning electron microscopy, energy dispersive analysis, X-ray phase analysis, and X-ray photoelectron spectroscopy. A comparative analysis of lead ion sorption on the surface of synthesized nanoparticles was conducted. The kinetic study revealed that the sorption process follows a pseudo-second-order mechanism, and the Freundlich sorption model provides a better fit for the experimental data. ZnO and CuO nanoparticles exhibited significant sorption capacities, with values of 163.6 and 153.8 mg g−1, respectively.

UR - https://www.scopus.com/pages/publications/85171869353

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DO - 10.1039/d3ra05347d

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SN - 2046-2069

VL - 13

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EP - 26850

JO - RSC Advances

JF - RSC Advances

IS - 38

ER -

Adsorption isotherms and kinetics for Pb(ii) ion removal from aqueous solutions with biogenic metal oxide nanoparticles

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