Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products

Fatih Algi; Tuncer Hökelek; Metin Balci

doi:10.3184/0308234043431906

Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products

Fatih Algi
, Tuncer Hökelek
, Metin Balci

Hacettepe University

Middle East Technical University
Canakkale Onsekiz Mart University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.

Original language	English
Pages (from-to)	658-660
Number of pages	3
Journal	Journal of Chemical Research - Part S
Issue number	10
DOIs	https://doi.org/10.3184/0308234043431906
Publication status	Published - Oct 2004

Keywords

Carbene
Carbene addition
Cyclobutene
Cyclopropane

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10.3184/0308234043431906

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title = "Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products",

abstract = "Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.",

keywords = "Carbene, Carbene addition, Cyclobutene, Cyclopropane",

author = "Fatih Algi and Tuncer H{\"o}kelek and Metin Balci",

year = "2004",

month = oct,

doi = "10.3184/0308234043431906",

language = "English",

pages = "658--660",

journal = "Journal of Chemical Research - Part S",

issn = "0308-2342",

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number = "10",

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TY - JOUR

T1 - Addition of dibromocarbene to cyclobutene

T2 - Characterisation and mechanism of formation of the products

AU - Algi, Fatih

AU - Hökelek, Tuncer

AU - Balci, Metin

PY - 2004/10

Y1 - 2004/10

N2 - Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.

AB - Cyclobutene reacted with dibromocarbene in solution to give 1,5-dibromocyclopent-1-ene (9), 1,2,6, 6-tetrabromobicyclo[3.1.0]hexane (10), and 1,2,3,6-tetrabromocyclohex-1-ene (11), in a ratio of 1:4:8, respectively. Compounds 10 and 11 were found to be formed from a second carbene addition and rearrangement under the given reaction conditions.

KW - Carbene

KW - Carbene addition

KW - Cyclobutene

KW - Cyclopropane

UR - https://www.scopus.com/pages/publications/10944233225

U2 - 10.3184/0308234043431906

DO - 10.3184/0308234043431906

M3 - Article

AN - SCOPUS:10944233225

SN - 0308-2342

SP - 658

EP - 660

JO - Journal of Chemical Research - Part S

JF - Journal of Chemical Research - Part S

IS - 10

ER -

Addition of dibromocarbene to cyclobutene: Characterisation and mechanism of formation of the products

Abstract

Keywords

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