A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

Seda Cinar; Baris Temelli; Canan Unaleroglu

doi:10.1016/j.tetlet.2013.11.101

A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

Seda Cinar
, Baris Temelli
, Canan Unaleroglu

Division of Organic Chemistry (Science, Faculty of Science and Literature, Faculty of Basic Sciences)

Hacettepe University

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.

Original language	English
Pages (from-to)	544-547
Number of pages	4
Journal	Tetrahedron Letters
Volume	55
Issue number	2
DOIs	https://doi.org/10.1016/j.tetlet.2013.11.101
Publication status	Published - 8 Jan 2014

Keywords

Expanded porphyrin
Hexaphyrin
N-sulfonyl aldimine
Tripyrrane

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10.1016/j.tetlet.2013.11.101

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abstract = "The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.",

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T2 - N-sulfonyl aldimine

AU - Cinar, Seda

AU - Temelli, Baris

AU - Unaleroglu, Canan

PY - 2014/1/8

Y1 - 2014/1/8

N2 - The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.

AB - The selective synthesis of [26]hexaphyrin(1.1.1.1.1.1) has been achieved by the reaction of meso-substituted tripyrrane and N-sulfonyl aldimine. The protocol is simple and requires only a catalytic amount of copper(II) triflate under mild reaction conditions.

KW - Expanded porphyrin

KW - Hexaphyrin

KW - N-sulfonyl aldimine

KW - Tripyrrane

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ER -

A new reagent for the synthesis of [26]hexaphyrin: N-sulfonyl aldimine

Abstract

Keywords

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