Abstract
The asymmetric unit of the title compound, C 21H 13N 3O 2, contains two independent molecules with a similar structure. In one molecule, the central benzene ring is oriented with respect to the terminal benzene rings at 27.23 (7) and 67.96 (7)°; in the other molecule, the corresponding dihedral angles are 12.42 (7) and 64.55 (7)°. In both molecules, there is a short O - H⋯N interaction involving the OH group and the adjacent N atom. In the crystal, there are O - H⋯N hydrogen bonds, and C - H⋯O and N - H⋯O interactions linking the molecules to form a three-dimensional network. π-π stacking between the pyridine and benzene rings and between the benzene rings [centroid-centroid distances = 3.989 (2), 3.705 (2) and 3.607 (2) Å] may further stabilize the structure. A weak C - H⋯π interaction is present in the crystal.
| Original language | English |
|---|---|
| Pages (from-to) | o565-o566 |
| Journal | Acta Crystallographica Section E: Structure Reports Online |
| Volume | 68 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - Mar 2012 |
Keywords
- R factor = 0.052
- T = 100 K
- data-to-parameter ratio = 17.1
- mean σ(C-C) = 0.003 Å
- single-crystal X-ray study
- wR factor = 0.148
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