1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Firudin I. Guseinov; Aida I. Samigullina; Tuncer Hökelek; Sahil Z. Hamidov; Jamal Lasri; Khudayar I. Hasanov; Tahir A. Javadzade; Alebel N. Belay

doi:10.1107/S2414314625004663

1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Firudin I. Guseinov
, Aida I. Samigullina
, Tuncer Hökelek
, Sahil Z. Hamidov
, Jamal Lasri
, Khudayar I. Hasanov
, Tahir A. Javadzade
, Alebel N. Belay

Hacettepe University

Moscow State University of Design and Technology
Russian Academy of Sciences
Azerbaijan Technological University
King Abdulaziz University
Western Caspian University
Azerbaycan Tibb Universiteti
Khazar University
Bahar Dar University

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, 0.638C₂₃H₁₆BrF₃N₂·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

Original language	English
Article number	x250466
Pages (from-to)	x250466
Journal	IUCrData
Volume	10
Issue number	Pt 6
DOIs	https://doi.org/10.1107/S2414314625004663
Publication status	Published - 1 Jun 2025

Keywords

crystal structure
hydrogen bond
pyrazole

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10.1107/S2414314625004663

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@article{ee26c842e80c42dc906849e4aed2012e,

title = "1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)",

abstract = "In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1\%), H⋯F/F⋯H (21.4\%) and H⋯C/C⋯H (18.9\%) interactions.",

keywords = "crystal structure, hydrogen bond, pyrazole",

author = "Guseinov, \{Firudin I.\} and Samigullina, \{Aida I.\} and Tuncer H{\"o}kelek and Hamidov, \{Sahil Z.\} and Jamal Lasri and Hasanov, \{Khudayar I.\} and Javadzade, \{Tahir A.\} and Belay, \{Alebel N.\}",

note = "Publisher Copyright: {\textcopyright} Guseinov et al. 2025.",

year = "2025",

month = jun,

day = "1",

doi = "10.1107/S2414314625004663",

language = "English",

volume = "10",

pages = "x250466",

journal = "IUCrData",

issn = "2414-3146",

publisher = "International Union of Crystallography",

number = "Pt 6",

}

TY - JOUR

T1 - 1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

AU - Guseinov, Firudin I.

AU - Samigullina, Aida I.

AU - Hökelek, Tuncer

AU - Hamidov, Sahil Z.

AU - Lasri, Jamal

AU - Hasanov, Khudayar I.

AU - Javadzade, Tahir A.

AU - Belay, Alebel N.

N1 - Publisher Copyright: © Guseinov et al. 2025.

PY - 2025/6/1

Y1 - 2025/6/1

N2 - In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

AB - In the title compound, 0.638C23H16BrF3N2·0.362C23H17F3N2, the Br atom has been partially replaced by an H atom by reaction with NaH. In the crystal, pairwise C-H⋯Br hydrogen bonds link the molecules into centrosymmetric dimers, enclosing R22(16) ring motifs. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯H (40.1%), H⋯F/F⋯H (21.4%) and H⋯C/C⋯H (18.9%) interactions.

KW - crystal structure

KW - hydrogen bond

KW - pyrazole

UR - https://www.scopus.com/pages/publications/105010600489

U2 - 10.1107/S2414314625004663

DO - 10.1107/S2414314625004663

M3 - Article

C2 - 40630054

AN - SCOPUS:105010600489

SN - 2414-3146

VL - 10

SP - x250466

JO - IUCrData

JF - IUCrData

IS - Pt 6

M1 - x250466

ER -

1-[(2-Bromophenyl)diphenylmethyl]-3-(trifluoromethyl)-1H-pyrazole-1-(triphenylmethyl)-3-(trifluoromethyl)-1H-pyrazole (0.638:0.362)

Abstract

Keywords

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